Allosterically coupled double induced fit for 1+1+1+1 self-assembly of a calix[6]trisamine, a calix[6]trisacid, and their guests

被引：42

作者：

Le Gac, Stephane

Marrot, Jerome

Reinaud, Olivia

Jabin, Ivan

机构：

[1] Univ Paris 06, UMR CNRS 8601, Lab Chim & Biochim Pharmacol & Toxicol, F-75270 Paris, France

[2] Univ Havre, URCOM, F-76058 Le Havre, France

[3] Univ Versailles, UMR CNRS 8637, Inst Lavoisier, F-78035 Versailles, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 19期

关键词：

allosterism; calixarenes; host-guest systems; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200503906

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Special guests: A cooperative double induced-fit process leads to the 1+1+1+1 self-assembly of quaternary complexes comprising two complementary calix[6]-arene-based hosts and their specific guests (see picture). The guests direct self-assembly by shaping their hosts. Such allosteric control involves multiple recognition levels reminiscent of those in biology. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3123 / 3126

页数：4

共 25 条

[1] SYNERGISM BETWEEN COENZYME AND ALCOHOL BINDING TO LIVER ALCOHOL-DEHYDROGENASE [J].