Contraction stress related to degree of conversion and reaction kinetics

被引:212
作者
Braga, RR
Ferracane, JL
机构
[1] Oregon Hlth Sci Univ, Sch Dent, Dept Biomat & Biomech, Portland, OR 97201 USA
[2] Univ Sao Paulo, Dept Dent Mat, BR-05508900 Sao Paulo, Brazil
关键词
composites; polymerization; contraction stress; volumetric shrinkage;
D O I
10.1177/154405910208100206
中图分类号
R78 [口腔科学];
学科分类号
1003 ;
摘要
Polymerization shrinkage of composites bonded to cavity preparations generates stress on the tooth/restoration interface. The purpose of this study was to verify the influence of degree of conversion and speed of polymerization reaction on contraction stress. We prepared experimental composites with different curing rates by varying the concentration of inhibitor (butylated hydroxytoluene). We verified the effect of degree of conversion by submitting one of the composites to different photo-activation times. Contraction stress was monitored for 10 minutes in a tensilometer. Fourier-transformed infrared spectrometry was used for assessment of the degree of conversion. Volumetric shrinkage was determined by means of a mercury dilatometer. Degree of conversion and volumetric shrinkage showed a non-linear relationship with energy density. Degree of conversion showed a pronounced influence on stress. Increased inhibitor concentration reduced curine, rate and contraction stress in composites, without compromising the final degree of conversion.
引用
收藏
页码:114 / 118
页数:5
相关论文
共 22 条
[11]   In vitro measurement of cuspal strain and displacement in composite restored teeth [J].
Meredith, N ;
Setchell, DJ .
JOURNAL OF DENTISTRY, 1997, 25 (3-4) :331-337
[12]  
Moad G., 1995, CHEM FREE RADICAL PO
[13]  
Odian G., 1991, PRINCIPLES POLYM, V3rd
[14]  
PAYNE MD, 2001, J DENT RES, V80, P250
[15]  
Rueggeberg F A, 1999, J Esthet Dent, V11, P197, DOI 10.1111/j.1708-8240.1999.tb00399.x
[16]   CALIBRATION OF FTIR CONVERSION ANALYSIS OF CONTEMPORARY DENTAL RESIN COMPOSITES [J].
RUEGGEBERG, FA ;
HASHINGER, DT ;
FAIRHURST, CW .
DENTAL MATERIALS, 1990, 6 (04) :241-249
[17]   Reduced light energy density decreases post-gel contraction while maintaining degree of conversion in composites [J].
Sakaguchi, RL ;
Berge, HX .
JOURNAL OF DENTISTRY, 1998, 26 (08) :695-700
[18]   Light intensity effects on resin-composite degree of conversion and shrinkage strain [J].
Silikas, N ;
Eliades, G ;
Watts, DC .
DENTAL MATERIALS, 2000, 16 (04) :292-296
[19]   POLYMERIZATION SHRINKAGE OF COMPOSITE RESINS - COMPARISON WITH TOOTH DEFORMATION [J].
SULIMAN, AH ;
BOYER, DB ;
LAKES, RS .
JOURNAL OF PROSTHETIC DENTISTRY, 1994, 71 (01) :7-12
[20]   POLYMERIZATION CONTRACTION AND CONVERSION OF LIGHT-CURING BISGMA-BASED METHACRYLATE RESINS [J].
VENHOVEN, BAM ;
DEGEE, AJ ;
DAVIDSON, CL .
BIOMATERIALS, 1993, 14 (11) :871-875