One-photon resonant optical nonlinearity of soluble substituted group IV metallophthalocyanines

被引：21

作者：

Henari, FZ ^{[1
]}

Callaghan, J ^{[1
]}

Blau, WJ ^{[1
]}

Haisch, P ^{[1
]}

Hanack, M ^{[1
]}

机构：

[1] UNIV TUBINGEN,INST ORGAN CHEM,D-72076 TUBINGEN,GERMANY

来源：

PURE AND APPLIED OPTICS | 1997年 / 6卷 / 06期

关键词：

D O I：

10.1088/0963-9659/6/6/016

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The synthesis and nonlinear optical characterization of highly soluble Ni-, Pd-and Pt-phthalocyanines is reported. When excited resonantly within the Q-band, the third-order nonlinearity chi((3)) is, dominated by saturable absorption, observed using the z-scan technique. The imaginary part of the nonlinear susceptibility chi((3)) was observed at 665 nm. From a three-level model, ground-state recovery times in the picosecond regime were determined for all phthalocyanines studied. These fast recovery times were supported by time-resolved measurements using degenerate four-wave mixing in the phase-conjugate geometry.

引用

页码：741 / 748

页数：8

共 24 条

[1] Bahae M.S., 1990, IEEE J QUANTUM ELECT, V26, P760
[2] REVERSE SATURABLE ABSORPTION IN TETRAPHENYLPORPHYRINS
BLAU, W
BYRNE, H
DENNIS, WM
KELLY, JM
[J]. OPTICS COMMUNICATIONS, 1985, 56 (01) : 25 - 29
[3] LANGMUIR-BLODGETT-FILM FORMATION OF A SERIES OF PERIPHERALLY OCTASUBSTITUTED METALLOPHTHALOCYANINES
BURGHARD, M
SCHMELZER, M
ROTH, S
HAISCH, P
HANACK, M
[J]. LANGMUIR, 1994, 10 (11) : 4265 - 4269
[4] WELL-ORGANIZED PHTHALOCYANINE LANGMUIR-BLODGETT-FILMS INCORPORATED INTO SYMMETRICAL (METAL/THIN ORGANIC FILM/METAL) SANDWICH STRUCTURES
BURGHARD, M
FISCHER, CM
SCHMELZER, M
ROTH, S
HAISCH, P
HANACK, M
[J]. SYNTHETIC METALS, 1994, 67 (1-3) : 193 - 195
[5] GAS SENSITIVITY OF SOME METAL PHTHALOCYANINES
COLLINS, RA
MOHAMMED, KA
[J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1988, 21 (01) : 154 - 161
[6] 3RD-ORDER NONLINEAR-OPTICAL PROPERTIES OF SOLUBLE OCTASUBSTITUTED METALLOPHTHALOCYANINES
DIAZGARCIA, MA
LEDOUX, I
DURO, JA
TORRES, T
AGULLOLOPEZ, F
ZYSS, J
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (35) : 8761 - 8764
[7] FLOM SR, 1992, MATER RES SOC S P, V274, P271
[8] RESONANT NONLINEAR OPTICAL-PROPERTIES OF SPIN-CAST FILMS OF SOLUBLE OLIGOMERIC BRIDGED (PHTHALOCYANINATO)RUTHENIUM(II) COMPLEXES
GRUND, A
KALTBEITZEL, A
MATHY, A
SCHWARZ, R
BUBECK, C
VERMEHREN, P
HANACK, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (18) : 7450 - 7454
[9] Soluble octasubstituted (phthalocyaninato) metal complexes
Haisch, P
Knecht, S
Schlick, U
Subramanian, LR
Hanack, M
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1995, 270 : 7 - 16
[10] HAISCH P, 1995, SYNTHESIS-STUTTGART, P1251

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