Promotion of low-temperature reduction behavior of the CeO2-ZrO2-Bi2O3 solid solution by addition of silver

被引：28

作者：

Imanaka, N ^{[1
]}

Masui, T ^{[1
]}

Minami, K ^{[1
]}

Koyabu, K ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

CHEMISTRY OF MATERIALS | 2005年 / 17卷 / 26期

关键词：

D O I：

10.1021/cm0519380

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effects of silver on the retention of the low-temperature reduction behavior of CeO2-ZrO2-Bi2O3 (CZB) were analyzed. The temperature-programmed reduction (TPR) trace of CZB displayed a reduction peak at 264°C. The Raman spectrum of CZB exhibited a strong band at 467 cm-1, which was assigned to the F2g mode of a cubic fluorite structure, and two minor peaks at 313 and 573 -1. The results show that silver somewhat dissolved into the CZB lattice after 10 cycles of redox aging.

引用

页码：6511 / 6513

页数：3

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