Synthesis of a cyclodextrin azo dye [3]rotaxane as a single isomer

被引:52
作者
Craig, MR
Claridge, TDW
Hutchings, MG
Anderson, HL
机构
[1] Univ Oxford, Dyson Perrins Lab, Dept Chem, Oxford OX1 3QY, England
[2] BASF plc, Cheadle Hulme SK8 6QG, Cheshire, England
关键词
D O I
10.1039/a902494h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Azo coupling between 2,6-dimethylphenol and aqueous 4,4'-bis(diazonio)azobenzene chloride in the presence of alpha-cyclodextrin yields an azo dye [3]rotaxane as a single stereoisomer, with the 2,3-rims of both cyclodextrins pointing outwards.
引用
收藏
页码:1537 / 1538
页数:2
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