Synthesis of a cyclodextrin azo dye [3]rotaxane as a single isomer

被引：52

作者：

Craig, MR

Claridge, TDW

Hutchings, MG

Anderson, HL

机构：

[1] Univ Oxford, Dyson Perrins Lab, Dept Chem, Oxford OX1 3QY, England

[2] BASF plc, Cheadle Hulme SK8 6QG, Cheshire, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 16期

关键词：

D O I：

10.1039/a902494h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Azo coupling between 2,6-dimethylphenol and aqueous 4,4'-bis(diazonio)azobenzene chloride in the presence of alpha-cyclodextrin yields an azo dye [3]rotaxane as a single stereoisomer, with the 2,3-rims of both cyclodextrins pointing outwards.

引用

页码：1537 / 1538

页数：2

共 23 条

[11] TRANSITION-METAL TEMPLATED FORMATION OF [2]-ROTAXANES AND [3]-ROTAXANES WITH PORPHYRINS AS STOPPERS
CHAMBRON, JC
HEITZ, V
SAUVAGE, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (26) : 12378 - 12384
[12] Synthesis of rotaxane assemblies
Dunnwald, T
Jager, R
Vogtle, F
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (12) : 2043 - 2051
[13] PREPARATION AND CHARACTERIZATION OF A POLYROTAXANE CONSISTING OF MONODISPERSE POLY(ETHYLENE GLYCOL) AND ALPHA-CYCLODEXTRINS
HARADA, A
LI, J
KAMACHI, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) : 3192 - 3196
[14] THE MOLECULAR NECKLACE - A ROTAXANE CONTAINING MANY THREADED ALPHA-CYCLODEXTRINS
HARADA, A
LI, J
KAMACHI, M
[J]. NATURE, 1992, 356 (6367) : 325 - 327
[15] EFFECT OF RING SIZE ON THREADING REACTIONS OF MACROCYCLES
HARRISON, IT
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (04) : 231 - &
[16] Molecular riveting: High yield preparation of a [3]-rotaxane
Kolchinski, AG
Alcock, NW
Roesner, RA
Busch, DH
[J]. CHEMICAL COMMUNICATIONS, 1998, (14) : 1437 - 1438
[17] Kinetics of the self-assembly of α-cyclodextrin [2]pseudorotaxanes with polymethylene threads bearing quaternary ammonium and phosphonium end groups
Lyon, AP
Banton, NJ
Macartney, DH
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1998, 76 (06): : 843 - 850
[18] A light-driven molecular shuttle based on a rotaxane
Murakami, H
Kawabuchi, A
Kotoo, K
Kunitake, M
Nakashima, N
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (32) : 7605 - 7606
[19] Cyclodextrin-based catenanes and rotaxanes
Nepogodiev, SA
Stoddart, JF
[J]. CHEMICAL REVIEWS, 1998, 98 (05) : 1959 - 1976
[20] A [3]rotaxane of the amide type
Vogtle, F
Dunnwald, T
Handel, M
Jager, R
Meier, S
Harder, G
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (06) : 640 - 643

← 1 2 3 →