Triazine-based Carbon Nitrides for Visible-Light-Driven Hydrogen Evolution

被引：400

作者：

Schwinghammer, Katharina ^{[1
,2
]}

Tuffy, Brian ^{[1
,2
]}

Mesch, Maria B. ^{[3
]}

Wirnhier, Eva ^{[2
]}

Martineau, Charlotte ^{[4
]}

Taulelle, Francis ^{[4
]}

Schnick, Wolfgang ^{[2
]}

Senker, Juergen ^{[3
]}

Lotsch, Bettina V. ^{[1
,2
]}

机构：

[1] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany

[2] Univ Munich, Dept Chem, D-81377 Munich, Germany

[3] Univ Bayreuth, Dept Inorgan Chem 3, D-95447 Bayreuth, Germany

[4] Univ Versailles St Quentin En Yvelines, Tectospin, ILV, UMR CNRS 8180, F-78035 Versailles, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 09期

关键词：

carbon nitrides; copolymerization; photocatalysis; triazines; water splitting; SOLID-STATE NMR; PHOTOCATALYTIC ACTIVITY; S-TRIAZINE; DERIVATIVES; CONDENSATION; ABSORPTION; MORPHOLOGY; CATALYSIS; MELEM; MELAM;

D O I：

10.1002/anie.201206817

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new dimension: The doping of amorphous poly(triazine imide) (PTI) through ionothermal copolymerization of dicyandiamide with 4-amino-2,6- dihydroxypyrimidine (4AP) results in triazine-based carbon nitrides with increased photoactivity for water splitting compared to crystalline poly(triazine imide) (PTI/Li+Cl-, see picture) and melon-type carbon nitrides. This family of carbon nitride semiconductors has potential as low-cost, environmentally clean photocatalysts for solar fuel production. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2435 / 2439

页数：5

共 39 条

[1] Enhanced photocatalytic activity of zeolite-encapsulated TiO2 clusters by complexation with organic additives and N-doping [J].

Alvaro, M ;

Carbonell, E ;

Fornés, V ;

García, H .

CHEMPHYSCHEM, 2006, 7 (01) :200-205

[2] Ionothermal Synthesis of Crystalline, Condensed, Graphitic Carbon Nitride [J].

Bojdys, Michael J. ;

Mueller, Jens-Oliver ;

Antonietti, Markus ;

Thomas, Arne .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (27) :8177-8182

[3] Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals [J].

Chen, Xiaobo ;

Liu, Lei ;

Yu, Peter Y. ;

Mao, Samuel S. .

SCIENCE, 2011, 331 (6018) :746-750

[4] Semiconductor-based Photocatalytic Hydrogen Generation [J].

Chen, Xiaobo ;

Shen, Shaohua ;

Guo, Liejin ;

Mao, Samuel S. .

CHEMICAL REVIEWS, 2010, 110 (11) :6503-6570

[5]

FINKELSTEIN AI, 1959, OPT SPEKTROSK+, V6, P33

[6]

Gervais C, 1998, MAGN RESON CHEM, V36, P407, DOI 10.1002/(SICI)1097-458X(199806)36:6<407::AID-OMR295>3.0.CO

[7]

2-Y

[8] State of Art and recent trends in bulk carbon nitrides synthesis [J].

Goglio, Graziella ;

Foy, Denis ;

Demazeau, Gerard .

MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2008, 58 (06) :195-227

[9] Steps on anatase TiO2(101) [J].

Gong, Xue-Qing ;

Selloni, Annabella ;

Batzill, Matthias ;

Diebold, Ulrike .

NATURE MATERIALS, 2006, 5 (08) :665-670

[10] Synthesis and Photocatalytic Activity of Poly(triazine imide) [J].

Ham, Yeilin ;

Maeda, Kazuhiko ;

Cha, Dongkyu ;

Takanabe, Kazuhiro ;

Domen, Kazunari .

CHEMISTRY-AN ASIAN JOURNAL, 2013, 8 (01) :218-224

← 1 2 3 4 →