Role of oxygen vacancy defect states in the n-type conduction of β-Ga2O3

被引:223
作者
Hajnal, Z
Miró, J
Kiss, G
Réti, F
Deák, P
Herndon, RC
Kuperberg, JM
机构
[1] Tech Univ Budapest, Dept Atom Phys, Ctr Hungarian Amer Environm Res Studies & Exchang, H-1111 Budapest, Hungary
[2] Res Inst Tech Phys & Mat Sci, H-1525 Budapest, Hungary
关键词
D O I
10.1063/1.371289
中图分类号
O59 [应用物理学];
学科分类号
摘要
Based on semiempirical quantum-chemical calculations, the electronic band structure of beta-Ga2O3 is presented and the formation and properties of oxygen vacancies are analyzed. The equilibrium geometries and formation energies of neutral and doubly ionized vacancies were calculated. Using the calculated donor level positions of the vacancies, the high temperature n-type conduction is explained. The vacancy concentration is obtained by fitting to the experimental resistivity and electron mobility. (C) 1999 American Institute of Physics. [S0021-8979(99)03318-6].
引用
收藏
页码:3792 / 3796
页数:5
相关论文
共 22 条
[1]  
[Anonymous], 1976, CHEM BONDS BONDS ENE
[2]  
Bernhardt K., 1995, Siemens Components (English Edition), V30, P35
[3]   RELATION BETWEEN ELECTRON BAND-STRUCTURE AND MAGNETIC BISTABILITY OF CONDUCTION ELECTRONS IN BETA-GA2O3 [J].
BINET, L ;
GOURIER, D ;
MINOT, C .
JOURNAL OF SOLID STATE CHEMISTRY, 1994, 113 (02) :420-433
[4]   STUDY OF SOME SUPERFICIAL PHYSICO-CHEMICAL PROPERTIES OF GALLIUM OXIDE .1. EXAMINATION OF STRUCTURAL DEFECTS AND CHEMISORPTION OF OXYGEN AND HYDROGEN [J].
BOZONVERDURAZ, F ;
POTVIN, C ;
PANNETIER, G .
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1970, 67 (09) :1608-+
[5]   SPECIAL POINTS IN BRILLOUIN ZONE [J].
CHADI, DJ ;
COHEN, ML .
PHYSICAL REVIEW B, 1973, 8 (12) :5747-5753
[6]   THEORETICAL-STUDIES ON THE CORE STRUCTURE OF THE 450-DEGREES-C OXYGEN THERMAL DONORS IN SILICON [J].
DEAK, P ;
SNYDER, LC ;
CORBETT, JW .
PHYSICAL REVIEW B, 1992, 45 (20) :11612-11626
[7]   Recombination with larger than bandgap energy at centres on the surface of silicon microstructures [J].
Deak, P ;
Hajnal, Z ;
Miro, J .
THIN SOLID FILMS, 1996, 276 (1-2) :290-292
[8]   CHARACTERIZATION AND CRYSTALLITE GROWTH OF SEMICONDUCTING HIGH-TEMPERATURE-STABLE GA2O3 THIN-FILMS [J].
FLEISCHER, M ;
MEIXNER, H .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1992, 11 (24) :1728-1731
[9]   EFFECT OF THE SENSOR STRUCTURE ON THE STABILITY OF GA(2)O(3) SENSORS FOR REDUCING GASES [J].
FLEISCHER, M ;
HOLLBAUER, L ;
MEIXNER, H .
SENSORS AND ACTUATORS B-CHEMICAL, 1994, 18 (1-3) :119-124
[10]   H2-INDUCED CHANGES IN ELECTRICAL CONDUCTANCE OF BETA-GA2O3 THIN-FILM SYSTEMS [J].
FLEISCHER, M ;
GIBER, J ;
MEIXNER, H .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1992, 54 (06) :560-566