Polyoxometalate chain-like polymer:: the synthesis and crystal structure of a 1D compound, [Mo36O108(NO)4(MoO)2La2(H2O)28]n • 56nH2O

被引:40
作者
Liu, G [1 ]
Wei, YG [1 ]
Yu, Q [1 ]
Liu, Q [1 ]
Zhang, SW [1 ]
机构
[1] Peking Univ, Dept Chem, Beijing 100871, Peoples R China
基金
中国国家自然科学基金;
关键词
molybdenum; polyoxometalate; chain-like polymer; nanomolecular compound;
D O I
10.1016/S1387-7003(99)00119-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of {Mo-36(NO)(4)} with LaCl3 in the presence of NH2OH . HCl results in the formation of a novel chain-like polymer, [Mo36O108(NO)(4)(MoO)(2)La-2(H2O)(28)](n). 56nH(2)O, in which the (Mo-36(NO)(4)} units an linked to each other by two parallel La atoms. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:434 / 437
页数:4
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