Palladium-neocuproine catalyzed aerobic oxidation of alcohols in aqueous solvents

被引：56

作者：

Arends, IWCE ^{[1
]}

ten Brink, GJ ^{[1
]}

Sheldon, RA ^{[1
]}

机构：

[1] Delft Univ Technol, Lab Biocatalysis & Organ Chem, NL-2628 BL Delft, Netherlands

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 251卷 / 1-2期

关键词：

palladium; phenanthroline; alcohol oxidation; dioxygen; water;

D O I：

10.1016/j.molcata.2006.02.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An overview is presented on the performance of Pd-complexes with phenanthroline-type ligands that are highly active catalysts for alcohol oxidation in water as well as in water/polar co-solvent mixtures. The mechanistic details of this intriguingly active and stable Pd-species are summarized. The (neocuproine)Pd(OAc)(2) catalyst is unique in that it tolerates water, polar co-solvents and a wide variety of functional groups in the alcohol. Turnover frequencies of > 1500 h(-1) were achieved in the latter case and a series of alcohols was oxidized with 0.1-0.5 mol% of catalyst. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：246 / 254

页数：9

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