Phase-Morphology and Molecular Structure Correlations in Model Fullerene-Polymer Nanocomposites

被引：6

作者：

Bucknall, David G. ^{[1
]}

Bernardo, Gabriel ^{[2
]}

Shofner, Meisha L. ^{[1
]}

Nabankur, Deb ^{[1
]}

Raghavan, Dharmaraj ^{[3
]}

Sumpter, Bobby G. ^{[4
]}

Sides, Scott ^{[5
]}

Huq, Abul ^{[6
]}

Karim, Alamgir ^{[6
]}

机构：

[1] Georgia Inst Technol, MSE, 801 Ferst Dr NW, Atlanta, GA 30332 USA

[2] Univ Minho, Inst Polym & Compos, I3N, Guimaraes 4800-058, Portugal

[3] Howard Univ, Washington, DC USA

[4] CNMS, Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA

[5] Tech X Corp, Boulder, CO 80303 USA

[6] Univ Akron, Dept Polymer Engn, Akron, OH 44325 USA

来源：

POLYMER COMPOSITE MATERIALS: FROM MACRO, MICRO TO NANOSCALE | 2012年 / 714卷

关键词：

Fullerene; Neutron & x-ray scattering; Differential Scanning Calorimetry; Molecular Modelling; BLENDS; CELLS;

D O I：

10.4028/www.scientific.net/MSF.714.63

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In this work we have performed a systematic study of blends of [6,6]-phenyl C61 butyric acid methyl ester (PCBM) with the following amorphous and semi-crystalline polymers: atactic polystyrene (PS), syndiotactic polystyrene (syn-PS), poly(2-vinyl-naphthalene) (P2VN), poly(9-vinyl-phenanthrene) (P9VPh), poly(vinylidene-fluoride) (PVdF) and poly(3-hexyl-thiophene) (P3HT). Experimental measurements using DSC, x-ray and neutron scattering coupled with molecular modeling (MD and DFT) have been utilized to determine the solubility and phase morphology of these model polymer-fullerene blends.

引用

页码：63 / +

页数：2

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