Atropisomeric binaphthalene-core phosphacyclic derivatives in coordination chemistry and homogeneous catalysis

被引：33

作者：

Gladiali, S ^{[1
]}

Fabbri, D ^{[1
]}

机构：

[1] CNR,IST APPLICAZ TECN CHIM AVANZATE PROBLEMI AGRO,I-07100 SASSARI,ITALY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 05期

关键词：

phosphorus heterocycles; binaphthophosphole; atropisomerism; binaphthophosphepine; hydroformylations;

D O I：

10.1002/cber.19971300503

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Binaphthophospholes and binaphthophosphepines have recently been synthesized. These are the first representatives of a new class of chiral ligands that include within the same structure an endocyclic phosphorus donor, a local C-2 symmetry and an axially chiral core. In this review we discuss the synthesis, chemical behaviour and first applications in asymmetric catalysis of these novel derivatives.

引用

页码：543 / 554

页数：12

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