Intramolecular excimers based on rigidly-linked platinum(II) complexes: intense deep-red triplet luminescence in solution

被引：55

作者：

Develay, Stephanie ^{[1
]}

Williams, J. A. Gareth ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

DALTON TRANSACTIONS | 2008年 / 34期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b807668e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By linking together two cyclometallated, N boolean AND C boolean AND N-coordinated platinum(II) complexes through a xanthene core, intense luminescence in the red region of the spectrum is achieved in solution at room temperature (lambda(max) = 690 nm, Phi(lum) = 0.20, tau = 1.7 mu s in CH2Cl2) due to the efficient formation of an intramolecular excimer.

引用

收藏

页码：4562 / 4564

页数：3

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