Reactions of spiked and open chain cluster hydrides with Au complexes:: skeletal rearrangement and crystal structures of heterometallic clusters [Au2Ru4(CO)12(μ4-PCF3)(PMe3)2] and [Au2Ru4(CO)12(μ3-PCF3)2(PPh3)2]

被引：4

作者：

Ang, HG ^{[1
]}

Ang, SG ^{[1
]}

Du, SW ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 589卷 / 02期

关键词：

ruthenium; heterometallic cluster; molecular structure; spiked; open chain;

D O I：

10.1016/S0022-328X(99)00369-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the spiked cluster [Ru-4(CO)(13)(mu-H)(2)(mu(4)-PCF3)] with [Au(PMe3)Cl] in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) results in deprotonation and metal core rearrangement from spiked to butterfly, yielding the heterometallic cluster [Au2Ru4(CO)(12)(mu(4)-PCF3)(PMe3)(2)] 1. Reaction of the open chain cluster [Ru-4(CO)(12)(mu-H)(2)(mu(3)-PCF3)(2)] with [Au(PPh3)Cl] under similar conditions gives [Au2Ru4(CO)(12)(mu(3)-PCF3)(2)(PPh3)(2)] 2 where the hydrides are simply replaced by AuPPh3 fragments. Clusters 1 and 2 are characterised by spectroscopy and X-ray crystallography. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：133 / 137

页数：5

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