Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed C-O Bond Activation

被引：183

作者：

Li, Bi-Jie ^{[1
,2
,3
]}

Xu, Li ^{[1
,2
,3
,4
]}

Wu, Zhen-Hua ^{[1
,2
,3
]}

Guan, Bing-Tao ^{[1
,2
,3
]}

Sun, Chang-Liang ^{[1
,2
,3
]}

Wang, Bi-Qin ^{[4
]}

Shi, Zhang-Jie ^{[1
,2
,3
,5
]}

机构：

[1] Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China

[2] Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China

[3] Peking Univ, Green Chem Ctr, Beijing 100871, Peoples R China

[4] Sichuan Normal Univ, Dept Chem, Chengdu 610068, Sichuan, Peoples R China

[5] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 41期

关键词：

ALKYL-HALIDES; BETA-HYDROGENS; IRON CATALYSIS; ARYL CHLORIDES;

D O I：

10.1021/ja907281f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron-catalyzed cross-coupling of alkenyl/aryl carboxylates with primary alkyl Grignard reagent was described. This reaction brought a new family of electrophiles to iron catalysis. The combination of an inexpensive carboxylate electrophile and an iron catalyst would generate ample advantages.

引用

页码：14656 / +

页数：3

共 44 条

[41] MECHANISTIC STUDIES OF IRON CATALYSIS IN CROSS COUPLING OF ALKENYL HALIDES AND GRIGNARD-REAGENTS
SMITH, RS
KOCHI, JK
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (03) : 502 - 509
[42] VINYLATION OF GRIGNARD REAGENTS - CATALYSIS BY IRON
TAMURA, M
KOCHI, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (06) : 1487 - &
[43] Hydroxyphosphine Ligand for Nickel-Catalyzed Cross-Coupling through Nickel/Magnesium Bimetallic Cooperation
Yoshikai, Naohiko
Matsuda, Hirokazu
Nakamura, Eiichi
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (27) : 9590 - 9599
[44] Novel substrates for palladium-catalyzed coupling reactions of arenes
Zapf, A
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (44) : 5394 - 5399

← 1 2 3 4 5 →