Solvent effects on chain orientation and interchain π-interaction in conjugated polymer thin films:: Direct measurements of the air and substrate interfaces by near-edge X-ray absorption spectroscopy

被引：97

作者：

Ho, Peter K. -H.

Chua, Lay-Lay

Dipankar, Mandal

Gao, Xingyu

Qi, Dongchen

Wee, Andrew T-S.

Chang, Jui-Fen

Friend, Richard H.

机构：

[1] Natl Univ Singapore, Dept Phys, Singapore 117548, Singapore

[2] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England

来源：

ADVANCED MATERIALS | 2007年 / 19卷 / 02期

关键词：

D O I：

10.1002/adma.200601285

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The orientation and pi-interaction of the frontier layers of regioregular poly(3-hexyl-thiophene) at both the air and substrate interfaces are directly measured for the first time using near-edge X-ray absorption fine-structure spectroscopy for thin films cast from a series of solvents (see figure). Results suggest the already high hole mobility in this material is still substantially limited by disorder at the interfaces.

引用

页码：215 / +

页数：8

共 43 条

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