Highly sensitive electrochemical detection of trace liquid peroxide explosives at a Prussian-blue 'artificial-peroxidase' modified electrode

被引：67

作者：

Lu, Donglai

Cagan, Avi

Munoz, Rodrigo A. A.

Tangkuaram, Tanin

Wang, Joseph ^{[1
]}

机构：

[1] Arizona State Univ, Biodesign Inst, Tempe, AZ 85287 USA

[2] Arizona State Univ, Dept Chem & Chem Engn, Tempe, AZ 85287 USA

来源：

ANALYST | 2006年 / 131卷 / 12期

关键词：

D O I：

10.1039/b613092e

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A highly sensitive electrochemical assay of the peroxide-based explosives triacetone triperoxide ( TATP) and hexamethylene triperoxide diamine ( HMTD) at a Prussian-blue (PB) modified electrode is reported. The method involves photochemical degradation of the peroxide explosives and a low potential (0.0 V) electrocatalytic amperometric sensing of the generated hydrogen peroxide at the PB transducer and offers nanomolar detection limits following a short ( 15 s) irradiation times. The electrochemical sensing protocol should facilitate rapid field screening of peroxide explosives.

引用

页码：1279 / 1281

页数：3

共 17 条

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[2]

2-Z

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