Reactivity studies of anticancer active dirhodium complexes with 2-aminothiophenol

被引：32

作者：

Sorasaenee, K ^{[1
]}

Galán-Mascarós, JR ^{[1
]}

Dunbar, KR ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 02期

关键词：

D O I：

10.1021/ic010799v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions between the antitumor active compound [Rh-2(II,II)(mu-O2CCH3)(2)(phen)(2)(CH3CN)(2)][PF6](2) (phen = 1,10-phenanthroline) and excess 2-aminothiophenol in the presence of oxygen yields the neutral complex [Rh-III(eta(2)- C6H6NS)(eta(1)-C6H6NS)(2)(phen)] (2), which was characterized by spectroscopic and crystallographic methods. Dinuclear intermediates are most likely involved in this chemistry as indicated by the isolation of [Rh-2(III,III)(mu-C6H6NS)(2)(C6H6NS)(2)(bPY)(2)](2+) (3a) as well as [Rh-III(C6H6NS)(2)(bpy)](+) (3b) from reactions of Rh-2(II,II)(mu-O2CCH3)(2)(bpy)(2)(CH3CN)(2) with 4 equiv of 2-aminothiophenol.

引用

页码：433 / +

页数：5

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