The role of bent acyclic allene gold complexes in axis-to-center chirality transfers

被引：113

作者：

Gandon, Vincent ^{[1
]}

Lemiere, Gilles ^{[1
]}

Hours, Alexandra ^{[1
]}

Fensterbank, Louis ^{[1
]}

Malacria, Max ^{[1
]}

机构：

[1] Univ Paris 06, Chim Organ Lab, UMR 7611, Inst Chim Mol FR2769, F-75252 Paris, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 39期

关键词：

allenes; density functional calculations; gold; homogeneous catalysis;

D O I：

10.1002/anie.200802332

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Activation of allenes toward nucleophilic attack by gold complexes ([Au], see scheme) often proceeds with axis-to-center chirality transfer. The stereochemical information is shown to be maintained in not only η2 allene complexes, but also in bent η1 allene complexes. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7534 / 7538

页数：5

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