Golden opportunities in stereoselective catalysis

被引：380

作者：

Bongers, Nadine ^{[1
]}

Krause, Norbert ^{[1
]}

机构：

[1] Dortmund Univ Technol, D-44227 Dortmund, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 12期

关键词：

chirality transfer; cycloisomerization; enantioselectivity; gold; ion pairs;

D O I：

10.1002/anie.200704729

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A golden future: The recent discoveries in stereoselective gold catalysis are extremely promising. Transfer of chirality or the generation of new stereogenic centers from prochiral substrates on application of chiral gold catalysts occur with excellent enantioselectivities. New concepts, such as the use of gold catalysts with chiral counterions, help to improve selectivities (see scheme, dppm=bis(diphenylphosphanyl) methane). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：2178 / 2181

页数：4

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