Self-Assembly of a Heteropolyoxopalladate Nanocube: [PdII13AsV8O34(OH)6]8-

被引：122

作者：

Chubarova, Elena V. ^{[1
]}

Dickman, Michael H. ^{[1
]}

Keita, Bineta ^{[2
]}

Nadjo, Louis ^{[2
]}

Miserque, Frederic ^{[3
]}

Mifsud, Maria ^{[4
]}

Arends, Isabel W. C. E. ^{[4
]}

Kortz, Ulrich ^{[1
]}

机构：

[1] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany

[2] Univ Paris 11, Chim Phys Lab, Paris, France

[3] CEA Saclay, DEN, DANS, DPC,SCP,Lab React Surfaces & Interfaces, F-91191 Gif Sur Yvette, France

[4] Delft Univ Technol, Dept Biotechnol, NL-2600 AA Delft, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 49期

关键词：

electrochemistry; nanoclusters; oxidation catalysis; palladium; polyoxometalates;

D O I：

10.1002/anie.200803527

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Not like the others: A molecular palladium oxide cluster was formed by self-assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [Pd II13AsV8O34(OH) 6]8- has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four-coordinate square-planar geometry, in marked contrast to all other known discrete polyoxometalates. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9542 / 9546

页数：5

共 51 条

[1] Chiral hydroperoxides as oxygen source in the catalytic stereoselective epoxidation of allylic alcohols by sandwich-type polyoxometalates:: Control of enantioselectivity through a metal-coordinated template [J].

Adam, W ;

Alsters, PL ;

Neumann, R ;

Saha-Möller, CR ;

Seebach, D ;

Beck, AK ;

Zhang, R .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (21) :8222-8231

[2] A highly chemoselective, diastereoselective, and regioselective epoxidation of chiral allylic alcohols with hydrogen peroxide, catalyzed by sandwich-type polyoxometalates:: Enhancement of reactivity and control of selectivity by the hydroxy group through metal-alcoholate bonding [J].

Adam, W ;

Alsters, PL ;

Neumann, R ;

Saha-Möller, CR ;

Sloboda-Rozner, D ;

Zhang, R .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (05) :1721-1728

[3] Spontaneous ordering of oxide nanostructures [J].

Aggarwal, S ;

Monga, AP ;

Perusse, SR ;

Ramesh, R ;

Ballarotto, V ;

Williams, ED ;

Chalamala, BR ;

Wei, Y ;

Reuss, RH .

SCIENCE, 2000, 287 (5461) :2235-2237

[4] RETRACTED: A palladium-oxo complex. Stabilization of this proposed catalytic intermediate by an encapsulating polytungstate ligand (Retracted Article) [J].

Anderson, TM ;

Cao, R ;

Slonkina, E ;

Hedman, B ;

Hodgson, KO ;

Hardcastle, KI ;

Neiwert, WA ;

Wu, SX ;

Kirk, ML ;

Knottenbelt, S ;

Depperman, EC ;

Keita, B ;

Nadjo, L ;

Musaev, DG ;

Morokuma, K ;

Hill, CL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (34) :11948-11949

[5] A palladium-oxo complex. Stabilization of this proposed catalytic intermediate by an encapsulating polytungstate ligand (vol 127, pg 11948, 2005) [J].

Anderson, Travis M. ;

Cao, Rui ;

Slonkina, Elena ;

Hedman, Britt ;

Hodgson, Keith O. ;

Hardcastle, Kenneth I. ;

Neiwert, Wade A. ;

Wu, Shaoxiong ;

Kirk, Martin L. ;

Knottenbelt, Sushilla ;

Depperman, Ezra C. ;

Keita, Bineta ;

Nadjo, Louis ;

Musaev, Djamaladdin G. ;

Morokuma, Keiji ;

Hill, Craig L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (09) :2877-2877

[6] A NOVEL HETEROPOLYMETALATE CONTAINING PALLADIUM(II) - SYNTHESIS AND CRYSTAL-STRUCTURE OF K2NA6[PD2W10O36]CENTER-DOT-22H(2)O [J].

ANGUSDUNNE, SJ ;

BURNS, RC ;

CRAIG, DC ;

LAWRANCE, GA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) :523-524

[7] Palladium-neocuproine catalyzed aerobic oxidation of alcohols in aqueous solvents [J].

Arends, IWCE ;

ten Brink, GJ ;

Sheldon, RA .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 251 (1-2) :246-254

[8] The palladium(II)-substituted, lone pair containing tungstoarsenates(III) [Na2(H2O)2PdWO(H2O)(α-AsW9O33)2]10- and [CS2Na(H2O)8Pd3(α-AsW9O33)2]9- [J].

Bi, LH ;

Kortz, U ;

Keita, B ;

Nadjo, L ;

Daniels, L .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (15) :3034-3041

[9] Palladium(II)-substituted tungstosilicate [Cs2K(H2O)7Pd2WO(H2O)(A-α-SiW9O34)2]9- [J].

Bi, LH ;

Kortz, U ;

Keita, B ;

Nadjo, L ;

Borrmann, H .

INORGANIC CHEMISTRY, 2004, 43 (26) :8367-8372

[10] First structurally characterized palladium(II)-substituted polyoxoanion:: [Cs2Na(H2O)10Pd3(α-SbIIIW9O33)2]9- [J].

Bi, LH ;

Reicke, M ;

Kortz, U ;

Keita, B ;

Nadjo, L ;

Clark, RJ .

INORGANIC CHEMISTRY, 2004, 43 (13) :3915-3920

← 1 2 3 4 5 6 →