Self-Assembly of a Heteropolyoxopalladate Nanocube: [PdII13AsV8O34(OH)6]8-

被引：122

作者：

Chubarova, Elena V. ^{[1
]}

Dickman, Michael H. ^{[1
]}

Keita, Bineta ^{[2
]}

Nadjo, Louis ^{[2
]}

Miserque, Frederic ^{[3
]}

Mifsud, Maria ^{[4
]}

Arends, Isabel W. C. E. ^{[4
]}

Kortz, Ulrich ^{[1
]}

机构：

[1] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany

[2] Univ Paris 11, Chim Phys Lab, Paris, France

[3] CEA Saclay, DEN, DANS, DPC,SCP,Lab React Surfaces & Interfaces, F-91191 Gif Sur Yvette, France

[4] Delft Univ Technol, Dept Biotechnol, NL-2600 AA Delft, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 49期

关键词：

electrochemistry; nanoclusters; oxidation catalysis; palladium; polyoxometalates;

D O I：

10.1002/anie.200803527

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Not like the others: A molecular palladium oxide cluster was formed by self-assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [Pd II13AsV8O34(OH) 6]8- has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four-coordinate square-planar geometry, in marked contrast to all other known discrete polyoxometalates. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9542 / 9546

页数：5

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