BiInO3:: A polar oxide with GdFeO3-type perovskite structure

被引：83

作者：

Belik, AA

Stefanovich, SY

Lazoryak, BI

Takayama-Muromachi, E

机构：

[1] NIMS, ICYS, Tsukuba, Ibaraki 3050044, Japan

[2] NIMS, AML, Tsukuba, Ibaraki 3050044, Japan

[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

来源：

CHEMISTRY OF MATERIALS | 2006年 / 18卷 / 07期

关键词：

D O I：

10.1021/cm052627s

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new oxide, BiInO3, was prepared using a high-pressure high-temperature technique at 6 GPa and 1273 K. BiInO3 has the GdFeO3-type perovskite structure, but crystallizes in the polar space group Pna2(1). Structure parameters of BiInO3 were refined from laboratory X-ray powder diffraction data (Z = 4; a = 5.95463(7) angstrom, b = 5.60182(7) angstrom, and c = 8.38631(11) angstrom). BiInO3 shows a second-harmonic generation signal of about 120-140 times that of quartz. BiInO3 decomposes at ambient pressure on heating above 873 K to give In2O3 and Bi25InO39. No phase transitions were found between 140 and 873 K using differential scanning calorimetry and differential thermal analysis. Vibrational properties of BiInO3 were studied by Raman spectroscopy.

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页码：1964 / 1968

页数：5

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