BiInO3:: A polar oxide with GdFeO3-type perovskite structure

被引：83

作者：

Belik, AA

Stefanovich, SY

Lazoryak, BI

Takayama-Muromachi, E

机构：

[1] NIMS, ICYS, Tsukuba, Ibaraki 3050044, Japan

[2] NIMS, AML, Tsukuba, Ibaraki 3050044, Japan

[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

来源：

CHEMISTRY OF MATERIALS | 2006年 / 18卷 / 07期

关键词：

D O I：

10.1021/cm052627s

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new oxide, BiInO3, was prepared using a high-pressure high-temperature technique at 6 GPa and 1273 K. BiInO3 has the GdFeO3-type perovskite structure, but crystallizes in the polar space group Pna2(1). Structure parameters of BiInO3 were refined from laboratory X-ray powder diffraction data (Z = 4; a = 5.95463(7) angstrom, b = 5.60182(7) angstrom, and c = 8.38631(11) angstrom). BiInO3 shows a second-harmonic generation signal of about 120-140 times that of quartz. BiInO3 decomposes at ambient pressure on heating above 873 K to give In2O3 and Bi25InO39. No phase transitions were found between 140 and 873 K using differential scanning calorimetry and differential thermal analysis. Vibrational properties of BiInO3 were studied by Raman spectroscopy.

引用

收藏

页码：1964 / 1968

页数：5

相关论文

共 50 条

[21] Density functional studies of multiferroic magnetoelectrics [J].

Hill, NA .

ANNUAL REVIEW OF MATERIALS RESEARCH, 2002, 32 :1-37

[22]

Hill NA, 2000, J PHYS CHEM B, V104, P6694, DOI [10.1021/jp000114x, 10.1021/jpc00114x]

[23] A polar oxide with a large magnetization synthesized at ambient pressure [J].

Hughes, H ;

Allix, MMB ;

Bridges, CA ;

Claridge, JB ;

Kuang, XJ ;

Niu, HJ ;

Taylor, S ;

Song, WH ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (40) :13790-13791

[24] Raman spectroscopy of orthorhombic perovskitelike YMnO3 and LaMnO3 [J].

Iliev, MN ;

Abrashev, MV ;

Lee, HG ;

Popov, VN ;

Sun, YY ;

Thomsen, C ;

Meng, RL ;

Chu, CW .

PHYSICAL REVIEW B, 1998, 57 (05) :2872-2877

[25] High-pressure synthesis and ferroelectric properties in perovskite-type BiScO3-PbTiO3 solid solution [J].

Inaguma, Y ;

Miyaguchi, A ;

Yoshida, M ;

Katsumata, T ;

Shimojo, Y ;

Wang, RP ;

Sekiya, T .

JOURNAL OF APPLIED PHYSICS, 2004, 95 (01) :231-235

[26] First-principles study of (BiScO3)1-x-(PbTiO3)x piezoelectric alloys -: art. no. 224107 [J].

Iñiguez, J ;

Vanderbilt, D ;

Bellaiche, L .

PHYSICAL REVIEW B, 2003, 67 (22)

[27] High pressure synthesis, crystal structure and physical properties of a new Ni(II) perovskite BiNiO3 [J].

Ishiwata, S ;

Azuma, M ;

Takano, M ;

Nishibori, E ;

Takata, M ;

Sakata, M ;

Kato, K .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (12) :3733-3737

[28] A Rietveld-analysis program RIETAN-98 and its applications to zeolites [J].

Izumi, F ;

Ikeda, T .

EUROPEAN POWDER DIFFRACTION, PTS 1 AND 2, 2000, 321-3 :198-203

[29] A versatile family of interconvertible microporous chiral molecular frameworks: The first example of ligand control of network chirality [J].

Kepert, CJ ;

Prior, TJ ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (21) :5158-5168

[30] Understanding the role of helical chains in the formation of noncentrosymmetric solids [J].

Maggard, PA ;

Stern, CL ;

Poeppelmeier, KR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (31) :7742-7743

← 1 2 3 4 5 →