Effect of deposition temperature and composition on the microstructure and electrical property of SrBi2Ta2O9 thin films prepared by metalorganic chemical vapor deposition

被引:29
作者
Nukaga, N [1 ]
Ishikawa, K [1 ]
Funakubo, H [1 ]
机构
[1] Tokyo Inst Technol, Interdisciplinary Grad Sch, Dept Innovat & Engineered Mat, Midori Ku, Yokohama, Kanagawa 2268502, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS | 1999年 / 38卷 / 9B期
关键词
SBT; trimethyl bismuth; strontium bis-hexamethoxy tantalate; MOCVD; step coverage;
D O I
10.1143/JJAP.38.5428
中图分类号
O59 [应用物理学];
学科分类号
摘要
SrBi2Ta2O9 (SBT) thin films were prepared by conventional thermal metalorganic chemical vapor deposition (MOCVD) and subsequent heat treatment. The SBT film deposited at 500 degrees C had a smoother surface and better step coverage than that deposited at 750 degrees C. The degree of step coverage deposited at 500 degrees C was 0.82. An almost single phase of SBT was obtained for the film with a Bi/Ta mole ratio of 1.0 by heat treatment at 750 degrees C for 30 min in O-2 atmosphere after MOCVD deposition at 500 degrees C, 2P(r) and E-C at an applied electric field of 620 kV/cm were 12.2 mu C/cm(2) and 87 kV/cm, respectively, when the film was deposited at 500 degrees C followed by heat treatment at 800 degrees C for 30 min in O-2 atmosphere, and its Bi/Ta ratio was 1.2.
引用
收藏
页码:5428 / 5431
页数:4
相关论文
共 12 条
[1]   Preparation and properties of ferroelectric Bi2SrTa2O9 thin films for FeRAM using flash-MOCVD [J].
Ami, T ;
Hironaka, K ;
Isobe, C ;
Nagel, N ;
Sugiyama, M ;
Ikeda, Y ;
Watanabe, K ;
Machida, A ;
Miura, K ;
Tanaka, M .
METAL-ORGANIC CHEMICAL VAPOR DEPOSITION OF ELECTRONIC CERAMICS II, 1996, 415 :195-200
[2]   PREPARATION OF BI-BASED FERROELECTRIC THIN-FILMS BY SOL-GEL METHOD [J].
ATSUKI, T ;
SOYAMA, N ;
YONEZAWA, T ;
OGI, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1995, 34 (9B) :5096-5099
[3]   FATIGUE-FREE FERROELECTRIC CAPACITORS WITH PLATINUM-ELECTRODES [J].
DEARAUJO, CAP ;
CUCHIARO, JD ;
MCMILLAN, LD ;
SCOTT, MC ;
SCOTT, JF .
NATURE, 1995, 374 (6523) :627-629
[4]  
EVERSTEYN FC, 1974, PHILIPS RES REP, V29, P45
[5]   Preparation of SrBi2Ta2O9 thin films by metalorganic chemical vapor deposition from two new liquid organometallic sources [J].
Funakubo, H ;
Nukaga, N ;
Ishikawa, K ;
Watanabe, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1999, 38 (2B) :L199-L201
[6]  
FUNAKUBO H, 1999, KEY ENG MATER, V169, P145
[7]  
Hartmann AJ, 1998, J KOREAN PHYS SOC, V32, pS1329
[8]   MOCVD of SrBi2Ta2O9 for integrated ferroelectric capacitors [J].
Hendrix, BC ;
Hintermaier, F ;
Desrochers, DA ;
Roeder, JF ;
Bhandari, G ;
Chappuis, M ;
Baum, TH ;
Van Buskirk, PC ;
Dehm, C ;
Fritsch, E ;
Nagel, N ;
Honlein, W ;
Mazure, C .
FERROELECTRIC THIN FILMS VI, 1998, 493 :225-230
[9]   Metalorganic chemical vapor deposition of epitaxial SrBi2Ta2O9 thin films and their crystal structure [J].
Ishikawa, K ;
Nukaga, N ;
Funakubo, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1999, 38 (3A) :L258-L260
[10]  
NUKAGA N, 1999, IN PRESS INTEGR FERR