Hydrosilylation of terminal alkynes with alkylidene ruthenium complexes and silanes

被引：61

作者：

Menozzi, C ^{[1
]}

Dalko, PI ^{[1
]}

Cossy, J ^{[1
]}

机构：

[1] Ecole Super Phys & Chim Ind Ville Paris, F-75231 Paris 05, France

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 26期

关键词：

D O I：

10.1021/jo051637+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium alkylidene complexes 1-3 mediate hydrosilylation of alkynes with silanes. When triethoxy- or triphenylsilanes are used as silylating agents, the reaction affords alpha-substituted vinylsilanes as major products.

引用

页码：10717 / 10719

页数：3

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