A near planar disilver complex of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine

被引:64
作者
Constable, EC [1 ]
Housecroft, CE [1 ]
Kariuki, BM [1 ]
Kelly, N [1 ]
Smith, CB [1 ]
机构
[1] Univ Birmingham, Sch Chem Sci, Birmingham B15 2TT, W Midlands, England
关键词
3,6-bis(2-pyridyl)-1,2,4,5-tetrazine; silver complex; crystal structure; supramolecular chemistry; grid;
D O I
10.1016/S1387-7003(02)00329-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The ligand 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine forms a 2:2 complex with silver(l) rather than the expected [4 x 4] grid, each of the two silver centres is in a near square-planar coordination environment. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:199 / 202
页数:4
相关论文
共 11 条
  • [1] Atwood J.L., 1973, CRYST STRUCT COMMUN, V2, P279
  • [2] A spontaneously resolved chiral molecular box:: a cyclic tetranuclear ZnII complex with DPTZ (DPTZ=3,6-di-2-pyridyl-1,2,4,5-tetrazine)
    Bu, XH
    Morishita, H
    Tanaka, K
    Biradha, K
    Furusho, S
    Shionoya, M
    [J]. CHEMICAL COMMUNICATIONS, 2000, (11) : 971 - 972
  • [3] Campos-Fernández CS, 1999, ANGEW CHEM INT EDIT, V38, P3477, DOI 10.1002/(SICI)1521-3773(19991203)38:23<3477::AID-ANIE3477>3.0.CO
  • [4] 2-P
  • [5] Fine-tuning the ring-size of metallacyclophanes:: A rational approach to molecular pentagons
    Campos-Fernández, CS
    Clérac, R
    Koomen, JM
    Russell, DH
    Dunbar, KR
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (04) : 773 - 774
  • [6] A polymeric sodium complex of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine
    Constable, EC
    Housecroft, CE
    Kariuki, BM
    Kelly, N
    Smith, CB
    [J]. CHEMICAL COMMUNICATIONS, 2001, (20) : 2134 - 2135
  • [7] CONSTABLE EC, 1986, ADV INORG CHEM RAD, V30, P6
  • [8] 2-D interwoven and 3-D 5-fold interpenetrating silver(I) complexes of 1-(isocyanidomethyl)-1H-benzotriazole and 1,3-bis(dicyanomethylidene)indan
    Ino, I
    Zhong, JC
    Munakata, M
    Kuroda-Sowa, T
    Maekawa, M
    Suenaga, Y
    Kitamori, Y
    [J]. INORGANIC CHEMISTRY, 2000, 39 (19) : 4273 - 4279
  • [9] Sauvage J.-P., 1999, PERSPECTIVES SUPRAMO, V5
  • [10] Influence of the counter ions and ligands on structures of silver(I) helicates with di-Schiff bases containing imidazole groups
    Yang, SP
    Chen, XM
    Ji, LN
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (14): : 2337 - 2343