Electrochemical properties of all-solid-state lithium secondary batteries using Li-argyrodite Li6PS5Cl as solid electrolyte

被引：80

作者：

Boulineau, Sylvain ^{[1
]}

Tarascon, Jean-Marie ^{[1
]}

Leriche, Jean-Bernard ^{[1
]}

Viallet, Virginie ^{[1
]}

机构：

[1] Univ Picardie Jules Verne, LRCS, CNRS UMR 7314, F-80039 Amiens, France

来源：

SOLID STATE IONICS | 2013年 / 242卷

关键词：

All-solid-state batteries; Lithium battery; Ionic conductors; Solid electrolytes; Argyrodite; Lithium ion conductivity; THIO-LISICON; CONDUCTOR; LICOO2;

D O I：

10.1016/j.ssi.2013.04.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solid-state electrolytes are being intensively explored as the key to develop all-solid-lithium secondary batteries which present safety advantages over present liquid Li-ion technology. To validate the use of the Li6PS5Cl-based solid electrolyte obtained by high energy ball milling, all-solid-state batteries using LiCoO2 and Li4Ti5O12 as active material (AM) have been realized. The optimization of the electrode composition led to a maximum of 46 and 27 mAh per gram of composite for LiCoO2 and Li4Ti5O12-based half-cells respectively. The assembled all-solid-state LiCoO2/Li6PS5Cl/Li4Ti5O12 battery presents a sustainable reversible capacity of 27 mAh per gram of AM and a coulombicic efficiency close to 99%. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：45 / 48

页数：4

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