Nucleophilic fluorine substitution of (eta(6)-fluoroarene) tricarbonylchromium complexes with dialkylphosphites

被引：3

作者：

Kirschke, K

Deutsch, J

Niclas, HJ

机构：

[1] Inst. Angew. Chem. Adlershof e. V., D-12484 Berlin

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1996年 / 117卷

关键词：

(eta(6)-dialkylphosphonoarene)tricarbonylchromium; dialkyl arylphosphonate; nucleophilic aromatic substitution;

D O I：

10.1080/10426509608038792

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The activation of fluoroarenes in their tricarbonylchromium complexes is used for the substitution of the fluoride with dialkyl phosphites under mild conditions. The resulting (eta 6-dialkyiphosphonoarene)tricarbonylchromium complexes 3a-f were characterized by IR, H-1, C-13, P-31 nmr and mass spectrometry. Using 3f the decomplexation to the dialkyl arylphosphonate 4 is demonstrated.

引用

页码：293 / 298

页数：6

共 8 条

[1]

[Anonymous], 1990, COMPREHENSIVE ORGANI

[2] SYNTHESIS OF 4-PHOSPHONO-DL-PHENYLALANINE AND OF 4-(PHOSPHONOMETHYL)-DL-PHENYLALANINE, 2 ANALOGS OF O-PHOSPHOTYROSINE [J].