Magnetically retrievable catalysts for organic synthesis

被引：613

作者：

Baig, R. B. Nasir ^{[1
]}

Varma, Rajender S. ^{[1
]}

机构：

[1] US EPA, Sustainable Technol Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 08期

关键词：

ATMOSPHERIC-PRESSURE CARBONYLATION; NANOPARTICLE-SUPPORTED PALLADIUM; N-HETEROCYCLIC CARBENES; BAYLIS-HILLMAN REACTION; CROSS-COUPLING REACTION; ASYMMETRIC HYDROGENATION; HETEROGENEOUS CATALYSIS; HOMOGENEOUS CATALYSIS; AEROBIC OXIDATION; SELECTIVE HYDROGENATION;

D O I：

10.1039/c2cc35663e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of magnetic nanoparticles (MNPs) as a catalyst support in organic synthesis is summarized. The recovery of expensive catalysts after catalytic reaction and reusing them without losing their activity is an essential feature in the sustainable process development. The aim of this article is to highlight the progress in the synthesis and catalytic applications of magnetic catalysts in organic synthesis. The heterogenization of the catalyst using magnetic nanoparticles allows it to be recovered and reused using an external magnet.

引用

页码：752 / 770

页数：19

共 188 条

[1] Metal supported on dendronized magnetic nanoparticles: Highly selective hydroformylation catalysts [J].

Abu-Reziq, R ;

Alper, H ;

Wang, DS ;

Post, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (15) :5279-5282

[2] Platinum nanoparticles supported on ionic liquid-modified magnetic nanoparticles: Selective hydrogenation catalysts [J].

Abu-Reziq, Raed ;

Wang, Dashan ;

Post, Michael ;

Alper, Howard .

ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (13) :2145-2150

[3] Phase transfer catalysis: some recent applications in organic synthesis [J].

Albanese, D ;

Landini, D ;

Maia, A ;

Penso, M .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 150 (1-2) :113-131

[4] 1,2,3-TRIAZOLE-[2',5'-BIS-O-(TERT-BUTYLDIMETHYLSILYL)-BETA-D-RIBOFURANOSYL]-3'-SPIRO-5''-(4''-AMINO-1'',2''-OXATHIOL 2'',2''-DIOXIDE) (TSAO) ANALOGS - SYNTHESIS AND ANTI-HIV-1 ACTIVITY [J].

ALVAREZ, R ;

VELAZQUEZ, S ;

SANFELIX, A ;

AQUARO, S ;

DECLERCQ, E ;

PERNO, CF ;

KARLSSON, A ;

BALZARINI, J ;

CAMARASA, MJ .

JOURNAL OF MEDICINAL CHEMISTRY, 1994, 37 (24) :4185-4194

[5]

Anastas P., 1998, GREEN CHEM THEORY PR

[6]

ANELLI PL, 1987, J ORG CHEM, V52, P2559

[7]

[Anonymous], 2008, Handbook of green chemistry and technology

[8] Organic-inorganic hybrid polymer-encapsulated magnetic nanobead catalysts [J].

Arai, Takayoshi ;

Sato, Toru ;

Kanoh, Hirofumi ;

Kaneko, Katsumi ;

Oguma, Koichi ;

Yanagisawa, Akira .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (03) :882-885

[9] Magnetically Separable Gold Catalyst for the Aerobic Oxidation of Amines [J].

Aschwanden, Linda ;

Panella, Barbara ;

Rossbach, Peggy ;

Keller, Beat ;

Baiker, Alfons .

CHEMCATCHEM, 2009, 1 (01) :111-115

[10] Stereo- and regio-selective one-pot synthesis of triazole-based unnatural amino acids and β-amino triazoles [J].

Baig, R. B. Nasir ;

Varma, Rajender S. .

CHEMICAL COMMUNICATIONS, 2012, 48 (47) :5853-5855

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