mu-oxo diferric complexes as oxidation catalysts with hydrogen peroxide and their potential in asymmetric oxidation

被引:59
作者
DubocToia, C [1 ]
Menage, S [1 ]
Lambeaux, C [1 ]
Fontecave, M [1 ]
机构
[1] UNIV GRENOBLE 1,F-38041 GRENOBLE 9,FRANCE
关键词
D O I
10.1016/S0040-4039(97)00710-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Non-heme diiron complexes, as models of methane monooxygenase, provide a new class of catalysts for oxidation reactions. We show here that such complexes have the potential for catalyzing stereoselective oxidations of sulfides by hydrogen peroxide. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:3727 / 3730
页数:4
相关论文
共 26 条
[1]  
ANDERSSON KK, 1991, NEW J CHEM, V15, P411
[2]  
ARENDS LWCE, 1995, J AM CHEM SOC, V117, P4710
[3]   THE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .20. ALKYL HYDROPEROXIDES - REACTION INTERMEDIATES IN THE OXIDATION OF SATURATED-HYDROCARBONS BY GIF-TYPE REACTIONS AND MECHANISTIC STUDIES ON THEIR FORMATION [J].
BARTON, DHR ;
BEVIERE, SD ;
CHAVASIRI, W ;
CSUHAI, E ;
DOLLER, D ;
LIU, WG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (06) :2147-2156
[4]  
Bolm C, 1995, ANGEW CHEM INT EDIT, V34, P2640
[5]  
Brunel JM, 1996, SYNLETT, P404
[6]   BIOMIMETIC OXIDATION STUDIES .5. MECHANISTIC ASPECTS OF ALKANE FUNCTIONALIZATION WITH FE,FE2O, AND FE4O2 COMPLEXES IN THE PRESENCE OF HYDROGEN-PEROXIDE [J].
FISH, RH ;
KONINGS, MS ;
OBERHAUSEN, KJ ;
FONG, RH ;
YU, WM ;
CHRISTOU, G ;
VINCENT, JB ;
COGGIN, DK ;
BUCHANAN, RM .
INORGANIC CHEMISTRY, 1991, 30 (15) :3002-3006
[7]  
GREEN J, 1989, J BIOL CHEM, V264, P17698
[8]   Effect of substituents in the ligand on oxidation of alkanes catalyzed by binuclear oxo-bridged iron complexes [J].
Gritsenko, ON ;
Nesterenko, GN ;
Shteinman, AA .
RUSSIAN CHEMICAL BULLETIN, 1995, 44 (12) :2415-2417
[9]   ASYMMETRIC HYDROXYLATION BY A CHIRAL IRON PORPHYRIN [J].
GROVES, JT ;
VISKI, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (22) :8537-8538
[10]   ASYMMETRIC HYDROXYLATION, EPOXIDATION, AND SULFOXIDATION CATALYZED BY VAULTED BINAPHTHYL METALLOPORPHYRINS [J].
GROVES, JT ;
VISKI, P .
JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (11) :3628-3634