Splitting CO2 into CO and O2 by a single catalyst

被引：169

作者：

Chen, Zuofeng ^{[1
]}

Concepcion, Javier J. ^{[1
]}

Brennaman, M. Kyle ^{[1
]}

Kang, Peng ^{[1
]}

Norris, Michael R. ^{[1
]}

Hoertz, Paul G. ^{[2
]}

Meyer, Thomas J. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

[2] RTI Int, Res Triangle Pk, NC 27709 USA

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2012年 / 109卷 / 39期

关键词：

artificial photosynthesis; polypyridyl Ru complexes; proton coupled electron transfer; single-site catalysis; solar fuels; COUPLED ELECTRON-TRANSFER; WATER OXIDATION; CARBON-DIOXIDE; ELECTROCATALYTIC REDUCTION; PHOTOSYSTEM-II; RUTHENIUM COMPLEX; BOND FORMATION; IRIDIUM; SITE; PHOTOSYNTHESIS;

D O I：

10.1073/pnas.1203122109

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The metal complex [(tpy)(Mebim-py)Ru-II(S)](2+) (tpy = 2,2' : 6'0,2 ''-terpyridine; Mebim-py = 3-methyl-1-pyridylbenzimidazol-2-ylidene; S = solvent) is a robust, reactive electrocatalyst toward both water oxidation to oxygen and carbon dioxide reduction to carbon monoxide. Here we describe its use as a single electrocatalyst for CO2 splitting, CO2 -> CO + 1/2O(2), in a two-compartment electrochemical cell.

引用

页码：15606 / 15611

页数：6

共 38 条

[21] Proton-coupled electron transfer [J].

Huynh, My Hang V. ;

Meyer, Thomas J. .

CHEMICAL REVIEWS, 2007, 107 (11) :5004-5064

[22] The greening of Synfuels [J].

Kintisch, Eli .

SCIENCE, 2008, 320 (5874) :306-308

[23] State of understanding of Nafion [J].

Mauritz, KA ;

Moore, RB .

CHEMICAL REVIEWS, 2004, 104 (10) :4535-4585

[24] Cyclometalated iridium(III) aquo complexes: Efficient and tunable catalysts for the homogeneous oxidation of water [J].

McDaniel, Neal D. ;

Coughlin, Frederick J. ;

Tinker, Leonard L. ;

Bernhard, Stefan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (01) :210-217

[25] The possible role of proton-coupled electron transfer (PCET) in water oxidation by photosystem II [J].

Meyer, Thomas J. ;

Huynh, My Hang V. ;

Thorp, H. Holden .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (28) :5284-5304

[26] Solar Fuels and Next Generation Photovoltaics: The UNC-CH Energy Frontier Research Center [J].

Meyer, Thomas J. ;

Papanikolas, John M. ;

Heyer, Catherine M. .

CATALYSIS LETTERS, 2011, 141 (01) :1-7

[27] Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels [J].

Morris, Amanda J. ;

Meyer, Gerald J. ;

Fujita, Etsuko .

ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (12) :1983-1994

[28] CARBON-CARBON BOND FORMATION IN THE ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE CATALYZED BY A RUTHENIUM COMPLEX [J].

NAGAO, H ;

MIZUKAWA, T ;

TANAKA, K .

INORGANIC CHEMISTRY, 1994, 33 (15) :3415-3420

[29] The complex architecture of oxygenic photosynthesis [J].

Nelson, N ;

Ben-Shem, A .

NATURE REVIEWS MOLECULAR CELL BIOLOGY, 2004, 5 (12) :971-982

[30] Structure and function of photosystems I and II [J].

Nelson, Nathan ;

Yocum, Charles F. .

ANNUAL REVIEW OF PLANT BIOLOGY, 2006, 57 :521-565

← 1 2 3 4 →