Allium chemistry: Synthesis of 1-[alk(en)ylsulfinyl]propyl alk(en)yl disulfides (cepaenes), antithrombotic flavorants from homogenates of onion (Allium cepa)

被引：27

作者：

Block, E

Gulati, H

Putman, D

Sha, DY

You, NN

Zhao, SH

机构：

[1] Department of Chemistry, State Univ. of New York at Albany, Albany

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1997年 / 45卷 / 11期

关键词：

Allium chemistry; onion (Allium cepa); a-sulfinyl disulfides; cepaenes; antithrombotic compounds;

D O I：

10.1021/jf9705126

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

A series of 1-[alk(en)ylsulfinyl]propyl alk(en)yl disulfides (alpha-sulfinyl disulfides) of structure RS(O)CHEtSSR', R, R' = Me, (E,Z)-MeCH=CH, n-Pr, and CH2=CHCH2, termed cepaenes, have been synthesized by a variety of routes including oxidation of 1-[alk(en)ylthio]propyl alk(en)yl disulfides, RSCHEtSSR', termed deoxycepaenes. The cepaenes are identical to compounds isolated from homogenates of onion (Allium cepa) and to compounds identified in these homogenates by liquid chromatography/mass spectrometry, while the deoxycepaenes are identical to compounds found in Allium distilled oils and in other materials: The antithrombotic activities for several cepaenes are reported.

引用

页码：4414 / 4422

页数：9

共 39 条

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