Direct episulfidation of caryophyllene and humulene

被引：13

作者：

Ashitani, T ^{[1
]}

Nagahama, S ^{[1
]}

机构：

[1] Kumamoto Inst Technol, Kumamoto 8600082, Japan

来源：

NATURAL PRODUCT LETTERS | 1999年 / 13卷 / 03期

关键词：

episulfidation; caryophyltene; humulene; medium ring olefin;

D O I：

10.1080/10575639908048781

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Caryophyllene-6,7-episulfide (3), humulene-9,10- (4) and -6,7-episulfide (5) found in hop oil, were prepared by heating caryophyllene or humulene with sulfur at 120 degrees C. Examination of various types of olefins showed that this peculiar reaction occurred only to the medium ring olefins.

引用

页码：163 / 167

页数：5

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