Comparison of Na1+xV3O8 with Li1+xV3O8 as lithium insertion host

被引：29

作者：

Kawakita, J ^{[1
]}

Miura, T ^{[1
]}

Kishi, T ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kouhoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

SOLID STATE IONICS | 1999年 / 124卷 / 1-2期

关键词：

sodium; vanadate; lithium; insertion; diffusion;

D O I：

10.1016/S0167-2738(99)00134-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lithium insertion behaviour of Na1+xV3O8 was studied and compared with that of Li1-xV3O8. The electrode potential and structural changes upon lithiation showed the presence of the primary single phase for 0 < x < 2.8 and the consecutive multi phases for 2.8 < x < 3.0 in LixNa1.2V3O8. Larger interlayer distance in Na1+xV3O8 contributed to a relaxation of interaction between inserted Li+ ions and did not improve a diffusivity of Li+ ion, compared with Li1+xV3O8. Lithium insertion and extraction was a reversible reaction. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：21 / 28

页数：8

共 26 条

[1] RECHARGEABLE LITHIUM VANADIUM-OXIDE CELLS UTILIZING 2ME-THF-LIASF6 [J].

ABRAHAM, KM ;

GOLDMAN, JL ;

DEMPSEY, MD .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (12) :2493-2501

[2]

Armand M. B., 1980, Materials for Advanced Batteries. Proceedings of a NATO Symposium on Materials for Advanced Batteries, P145

[3] Temperature dependence of lithium insertion behaviour of Li1+xV3O8 [J].

Kawakita, J ;

Kaji, R ;

Katayama, Y ;

Miura, T ;

Kishi, T .

DENKI KAGAKU, 1998, 66 (12) :1234-1235

[4] Charging characteristics of Li1+xV3O8 [J].

Kawakita, J ;

Miura, T ;

Kishi, T .

SOLID STATE IONICS, 1999, 118 (1-2) :141-147

[5] Preparation and lithium insertion behaviour of LiyNa1.2-yV3O8 [J].

Kawakita, J ;

Makino, K ;

Katayama, Y ;

Miura, T ;

Kishi, T .

SOLID STATE IONICS, 1997, 99 (3-4) :165-171

[6] Structural properties of Li1+3V3O8 upon lithium insertion at ambient and high temperature [J].

Kawakita, J ;

Katayama, Y ;

Miura, T ;

Kishi, T .

SOLID STATE IONICS, 1998, 107 (1-2) :145-152

[7] Lithium insertion behaviour of manganese or molybdenum substituted Li1+xV3O8 [J].

Kawakita, J ;

Katagiri, H ;

Miura, T ;

Kishi, T .

JOURNAL OF POWER SOURCES, 1997, 68 (02) :680-685

[8] Li1-xNaxV3O8 as positive materials for secondary lithium batteries [J].

Kumagai, N ;

Yu, A ;

West, K .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1997, 27 (08) :953-958

[9] STRUCTURAL-CHANGES OF NB2O5 AND V2O5 AS RECHARGEABLE CATHODES FOR LITHIUM BATTERY [J].

KUMAGAI, N ;

TANNO, K ;

NAKAJIMA, T ;

WATANABE, N .

ELECTROCHIMICA ACTA, 1983, 28 (01) :17-22

[10] VANADIUM-OXIDE CATHODE MATERIALS FOR SECONDARY LITHIUM CELLS [J].

MURPHY, DW ;

CHRISTIAN, PA ;

DISALVO, FJ ;

CARIDES, JN .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (03) :497-499

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