Solubility of carbon dioxide in water under incipient clathrate formation conditions

被引:70
作者
Anderson, GK [1 ]
机构
[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
关键词
D O I
10.1021/je015518c
中图分类号
O414.1 [热力学];
学科分类号
摘要
The solubility of carbon dioxide in water was measured at temperatures from 1 degreesC to 15 degreesC, at pressures approaching the clathrate-forming pressure. The goal was to fill gaps in the literature as well as to look for evidence of structural changes in liquid water near the onset of clathrate formation. The data were analyzed according to the Krichevsky-Kasarnovsky (KK) equation. The Henry's law constant K-H and the partial molar volume at infinite dilution (V) over bar (infinity)(CO2) were determined at each temperature. Contrary to claims based on older data in the literature, the KK equation was found to be an adequate representation of the solubility. The Henry's law constants are in excellent agreement with accepted literature values. No evidence was found for dramatic changes in water structure as the clathrate-forming pressure is approached.
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页码:219 / 222
页数:4
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