Electrochemical bond-breaking reactions: A comparison of large scale simulation results with analytical theory

被引：39

作者：

Calhoun, A

Koper, MTM

Voth, GA ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

[2] Univ Utah, Henry Eyring Ctr Theoret Chem, Salt Lake City, UT 84112 USA

[3] Eindhoven Univ Technol, Inorgan Chem & Catalysis Lab, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 1999年 / 103卷 / 17期

关键词：

D O I：

10.1021/jp984696i

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adiabatic free energy surface for the electrochemically induced dissociation of a methyl halide MeX (MeX + e(-) --> Me + X(-)) is computed from molecular dynamics (MD) simulations based on an underlying Hamiltonian developed to describe such processes. A two-dimensional free energy surface as a function of a collective solvent coordinate and the intramolecular Me-X bond length is computed. The theoretical basis of the simulations is a novel extension of the Anderson-Newns Hamiltonian to describe the coupling of the electron transfer to the bond-breaking process. A comparison of the simulation results is made with the standard analytical theory which is developed by virtue of several simplifying assumptions. It is found that the nonlinear microscopic features of the system produce significant deviations from the predictions of the analytical model.

引用

页码：3442 / 3448

页数：7