Three-center, two-electron M•••H-B bonds in complexes of Ni, Co, and Fe and the dihydrobis(3-tert-butylpyrazolyl) borate ligand

被引:37
作者
Belderraín, TR
Paneque, M
Carmona, E
Gutiérrez-Puebla, E
Monge, MA
Ruiz-Valero, C
机构
[1] Univ Seville, CSIC, Inst Invest Quim, Dept Quim Inorgan, Seville 41092, Spain
[2] Univ Huelva, Dept Quim & Ciencia Mat, Palos De La Frontera 21819, Huelva, Spain
[3] CSIC, Inst Ciencia Mat Madrid, E-28049 Madrid, Spain
关键词
D O I
10.1021/ic010598r
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Fe, Co, and Ni complexes of bulky Bp' ligands that contain two M...H-B three-center, two-electron interactions have been prepared and structurally characterized.
引用
收藏
页码:425 / +
页数:5
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共 43 条
[1]   NOVEL PYRAZOLYLBORATO-RUTHENIUM AND PYRAZOLYL-RUTHENIUM COMPLEXES - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [(H(MU-H)B(3,5-ME2PZ)2)RU(ETA-4-C8H12)H] AND [(ETA-4-C8H12)2RU2H(MU-N=C(ME)PZ)(MU-PZ)(MU-H)] CONFIRMATION OF THE 1ST EXAMPLES OF THE RU=H-B AGOSTIC INTERACTION AND THE BRIDGING AMIDINE LIGAND) [J].
ALBERS, MO ;
CROSBY, SFA ;
LILES, DC ;
ROBINSON, DJ ;
SHAVER, A ;
SINGLETON, E .
ORGANOMETALLICS, 1987, 6 (09) :2014-2017
[2]   Hydrotris(pyrazolyl)borato cycloocta-1,5-diene complexes of iridium(I): Synthetic studies and equilibria in solution. X-ray crystal structures of a four- and a five-coordinate iridium(I) hydrotris(pyrazolyl)borato complex [J].
Albinati, A ;
Bovens, M ;
Ruegger, H ;
Venanzi, LM .
INORGANIC CHEMISTRY, 1997, 36 (26) :5991-5999
[3]   ETHOXYCARBONYL-METHYL, CYANO-METHYL AND METHOXY-METHYL COMPLEXES OF NICKEL(II) AND THEIR CARBONYLATION REACTIONS [J].
BELDERRAIN, TR ;
KNIGHT, DA ;
IRVINE, DJ ;
PANEQUE, M ;
POVEDA, ML ;
CARMONA, E .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (09) :1491-1495
[4]   Synthesis and characterisation of bis- and tris-(pyrazol-1-yl)borate acetyl complexes of FeII and RuII and isolation of an intermediate of B-N bond hydrolysis [J].
Bellachioma, G ;
Cardaci, G ;
Gramlich, V ;
Macchioni, A ;
Pieroni, F ;
Venanzi, LM .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (06) :947-951
[5]   ORGANOMETALLIC CHEMISTRY OF PALLADIUM AND PLATINUM WITH POLY(PYRAZOL-1-YL)ALKANES AND POLY(PYRAZOL-1-YL)BORATES [J].
BYERS, PK ;
CANTY, AJ ;
HONEYMAN, RT .
ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1992, 34 :1-65
[6]   TRISPYRAZOLYLBORATE DEGRADATION IN RHODIUM COMPLEXES - CRYSTAL-STRUCTURE OF [RH(3-BU(T)-C3N2H2)(NBD)(3-BU(T)-C3N2H3)] [J].
CANO, M ;
CAMPO, JA ;
HERAS, JV ;
PINILLA, E ;
RIVAS, C ;
MONGE, A .
POLYHEDRON, 1994, 13 (15-16) :2463-2465
[7]   BORATROPIC REARRANGEMENTS IN TRIS(PYRAZOLYL)BORATE MOLYBDENUM MONONITROSYL COMPLEXES - EFFECTS OF CO-LIGANDS [J].
CANO, M ;
HERAS, JV ;
MONGE, A ;
PINILLA, E ;
SANTAMARIA, E ;
HINTON, HA ;
JONES, CJ ;
MCCLEVERTY, JA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (13) :2281-2288
[8]   ALKYL AND ACYL DERIVATIVES OF NICKEL(II) CONTAINING TERTIARY PHOSPHINE-LIGANDS [J].
CARMONA, E ;
GONZALEZ, F ;
POVEDA, ML ;
ATWOOD, JL ;
ROGERS, RD .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (11) :2108-2116
[9]   Steric control of the reactivity of moderately hindered tris(pyrazolyl)borates with copper(II) salts [J].
Chia, LML ;
Radojevic, S ;
Scowen, IJ ;
McPartlin, M ;
Halcrow, MA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (02) :133-140
[10]   New alkyl organo complexes of ruthenium: X-ray molecular structure of a [hydridotris(pyrazolyl)borato]methylruthenium complex, [RuTp*(CH3)(cod)] (Tp* equals hydridotris(3,5-dimethylpyrazolyl)borate, cod equals 1,5-cyclooctadiene), containing an unusual three-center B(mu-H)Ru bond [J].
Corrochano, AE ;
Jalon, FA ;
Otero, A ;
Kubicki, MM ;
Richard, P .
ORGANOMETALLICS, 1997, 16 (01) :145-148