Catalytic, highly enantio, and diastereoselective nitroso Diels-Alder reaction

被引：130

作者：

Yamamoto, Y ^{[1
]}

Yamamoto, H ^{[1
]}

机构：

[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 13期

关键词：

D O I：

10.1021/ja049849w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication presents studies that nitroso Diels?Alder adduct has been furnished in uniformly high yield and high enantioselectivity using nitrosopyridine as a substrate and copper as a catalyst. The obtained Diels?Alder adduct was easily transformed to corresponding chiral amino alcohols without loss of enantioselectivity. Copyright © 2004 American Chemical Society.

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页码：4128 / 4129

页数：2

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