Poly(ethylene glycol) as reaction medium for mild Mizoroki-Heck reaction in a ball-mill

被引：107

作者：

Declerck, Valerie

Colacino, Evelina

Bantreil, Xavier

Martinez, Jean

Lamaty, Frederic ^{[1
]}

机构：

[1] Univ Montpellier I, CNRS, IBMM, F-34095 Montpellier 5, France

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 96期

关键词：

SOLVENT-FREE SYNTHESIS; PALLADIUM NANOPARTICLES; RECYCLABLE CATALYST; MICROWAVE; PEG; EFFICIENT; SYSTEM;

D O I：

10.1039/c2cc36286d

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Phosphine-free palladium-catalyzed Mizoroki-Heck reaction was performed using ball-milling in polyethylene glycol under mild conditions. Good to excellent yields of coupling products were obtained. This activation technique also allowed the concomitant formation of round shaped Pd-PEG nanoparticles that were characterized by TEM analysis.

引用

收藏

页码：11778 / 11780

页数：3

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