Alternative energy input: mechanochemical, microwave and ultrasound-assisted organic synthesis

被引:468
作者
Baig, R. B. Nasir [1 ]
Varma, Rajender S. [1 ]
机构
[1] US EPA, Sustainable Technol Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA
关键词
BAYLIS-HILLMAN REACTION; SOLVENT-FREE SYNTHESIS; CROSS-COUPLING REACTIONS; AQUEOUS N-HETEROCYCLIZATION; ONE-POT SYNTHESIS; LIGAND-FREE; TRIMETHYLSILYL ETHERS; HECK REACTION; COPPER-FREE; OXIDATIVE DEPROTECTION;
D O I
10.1039/c1cs15204a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Microwave, ultrasound, sunlight and mechanochemical mixing can be used to augment conventional laboratory techniques. By applying these alternative means of activation, a number of chemical transformations have been achieved thereby improving many existing protocols with superior results when compared to reactions performed under traditional conditions. The purpose of this critical review is to highlight the advances in this general area by presenting such newer applications in organic synthesis (175 references).
引用
收藏
页码:1559 / 1584
页数:26
相关论文
共 237 条
[1]  
ABRAMOVITCH RA, 1991, ORG PREP PROCED INT, V23, P685
[2]   Reevaluation of the mechanism of the Baylis-Hillman reaction: Implications for asymmetric catalysis [J].
Aggarwal, VK ;
Fulford, SY ;
Lloyd-Jones, GC .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (11) :1706-1708
[3]   Aqueous sodium hydroxide promoted cross-coupling reactions of alkenyltrialkoxysilanes under ligand-free conditions [J].
Alacid, Emilio ;
Najera, Carmen .
JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (06) :2315-2322
[4]   The first fluoride-free Hiyama reaction of vinylsiloxanes promoted by sodium hydroxide in water [J].
Alacid, Emilio ;
Najera, Carmen .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (15) :2085-2091
[5]  
Alloum A. B., 1989, CHEM COMMUN, P386
[6]   Low temperature recyclable catalyst for Heck reactions using ultrasound [J].
Ambulgekar, GV ;
Bhanage, BM ;
Samant, SD .
TETRAHEDRON LETTERS, 2005, 46 (14) :2483-2485
[7]  
Anastas P. T., 2000, GREEN CHEM THEORY PR
[8]  
Ando T., 1991, Advances in Sonochemistry, V2, P211
[9]  
[Anonymous], 2003, SYNTHETIC COMMUN
[10]  
[Anonymous], 2011, CURR ORG CHEM, V15