Alternative energy input: mechanochemical, microwave and ultrasound-assisted organic synthesis

被引:468
作者
Baig, R. B. Nasir [1 ]
Varma, Rajender S. [1 ]
机构
[1] US EPA, Sustainable Technol Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA
关键词
BAYLIS-HILLMAN REACTION; SOLVENT-FREE SYNTHESIS; CROSS-COUPLING REACTIONS; AQUEOUS N-HETEROCYCLIZATION; ONE-POT SYNTHESIS; LIGAND-FREE; TRIMETHYLSILYL ETHERS; HECK REACTION; COPPER-FREE; OXIDATIVE DEPROTECTION;
D O I
10.1039/c1cs15204a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Microwave, ultrasound, sunlight and mechanochemical mixing can be used to augment conventional laboratory techniques. By applying these alternative means of activation, a number of chemical transformations have been achieved thereby improving many existing protocols with superior results when compared to reactions performed under traditional conditions. The purpose of this critical review is to highlight the advances in this general area by presenting such newer applications in organic synthesis (175 references).
引用
收藏
页码:1559 / 1584
页数:26
相关论文
共 237 条
[11]   A microwave-assisted click chemistry synthesis of 1,4-disubstituted 1,2,3-triazoles via a copper(I)-catalyzed three-component reaction [J].
Appukkuttan, P ;
Dehaen, W ;
Fokin, VV ;
Van der Eycken, E .
ORGANIC LETTERS, 2004, 6 (23) :4223-4225
[12]   Transition-metal-free Sonogashira-type coupling reactions in water [J].
Appukkuttan, P ;
Dehaen, W ;
Van der Eycken, E .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (24) :4713-4716
[13]   Facile reaction of thiols and amines with alkyl 4-hydroxy-2-alkynoates in water under neutral conditions and ultrasound irradiation [J].
Arcadi, Antonio ;
Alfonsi, Maria ;
Marinelli, Fabio .
TETRAHEDRON LETTERS, 2009, 50 (18) :2060-2064
[14]   Highly regioselective internal heck arylation of hydroxyalkyl vinyl ethers by aryl halides in water [J].
Arvela, Riina K. ;
Pasquini, Serena ;
Larhed, Mats .
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (17) :6390-6396
[15]   Bubbles in an acoustic field: An overview [J].
Ashokkumar, Muthupandian ;
Lee, Judy ;
Kentish, Sandra ;
Grieser, Franz .
ULTRASONICS SONOCHEMISTRY, 2007, 14 (04) :470-475
[16]   DIHYDROPYRIMIDINE CALCIUM-CHANNEL BLOCKERS .3. 3-CARBAMOYL-4-ARYL-1,2,3,4-TETRAHYDRO-6-METHYL-5-PYRIMIDINECARBOXYLIC ACID-ESTERS AS ORALLY EFFECTIVE ANTIHYPERTENSIVE AGENTS [J].
ATWAL, KS ;
SWANSON, BN ;
UNGER, SE ;
FLOYD, DM ;
MORELAND, S ;
HEDBERG, A ;
OREILLY, BC .
JOURNAL OF MEDICINAL CHEMISTRY, 1991, 34 (02) :806-811
[17]   Click Chemistry Under Microwave or Ultrasound Irradiation [J].
Barge, Alessandro ;
Tagliapietra, Silvia ;
Binello, Arianna ;
Cravotto, Giancarlo .
CURRENT ORGANIC CHEMISTRY, 2011, 15 (02) :189-203
[18]   Bulk Synthesis of Monodisperse Ferrite Nanoparticles at Water-Organic Interfaces under Conventional and Microwave Hydrothermal Treatment and Their Surface Functionalization [J].
Baruwati, Babita ;
Nadagouda, Mallikarjuna N. ;
Varma, Rajender S. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (47) :18399-18404
[19]   The Baylis-Hillman reaction: A novel carbon-carbon bond forming reaction [J].
Basavaiah, D ;
Rao, PD ;
Hyma, RS .
TETRAHEDRON, 1996, 52 (24) :8001-8062
[20]   Recent advances in the Baylis-Hillman reaction and applications [J].
Basavaiah, D ;
Rao, AJ ;
Satyanarayana, T .
CHEMICAL REVIEWS, 2003, 103 (03) :811-891