Release of nitric oxide from a sol-gel hybrid material containing a photoactive manganese nitrosyl upon illumination with visible light

被引：73

作者：

Eroy-Reveles, Aura A. ^{[1
]}

Leung, Yvonne ^{[1
]}

Mascharak, Pradip K. ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 22期

关键词：

D O I：

10.1021/ja061852n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polyurethane-coated sol-gel material containing the photoactive Mn nitrosyl [Mn(PaPy3)(NO)]ClO4 rapidly releases NO with high quantum efficiency when exposed to visible light of low intensity. This rigid and strongly colored hybrid material is a convenient point source of NO that can only be triggered with light. Successful delivery of NO to biological targets, such as proteins, by this material has also been demonstrated. Copyright © 2006 American Chemical Society.

引用

页码：7166 / 7167

页数：2

共 21 条

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