Anomalous low-temperature proton conductivity enhancement in a novel protonic nanocomposite

被引：19

作者：

Clark, D. ^{[1
]}

Tong, J. ^{[1
]}

Morrissey, A. ^{[1
]}

Almansoori, A. ^{[2
]}

Reimanis, I. ^{[1
]}

O'Hayre, R. ^{[1
]}

机构：

[1] Colorado Sch Mines, Dept Met & Mat Engn, Golden, CO 80401 USA

[2] Petr Inst, Dept Chem Engn, Abu Dhabi, U Arab Emirates

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2014年 / 16卷 / 11期

基金：

美国国家科学基金会;

关键词：

DOPED BARIUM ZIRCONATE; SINTERED OXIDES; ION CONDUCTION; MICROSTRUCTURE; BAZR0.1CE0.7Y0.1YB0.1O3-DELTA; TRANSPORT; DEFECT;

D O I：

10.1039/c4cp00468j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel protonic ceramic composite is synthesized that comprises nanoscale nickel metal films partially decorating the grain boundaries of the proton-conducting ceramic, BaCe(0.7)Zr(0.1)Y(0.1)Yb(0.1)O3-delta (BCZYYb). Low-temperature proton conductivity improvements of up to 46x vs. a control are observed, suggesting a novel method to enhance ion conductivity in polycrystalline materials.

引用

收藏

页码：5076 / 5080

页数：5

相关论文

共 35 条

[1] Effect of co-doping on proton conductivity in perovskite oxides BaZr0.9In0.05M0.05O3-δ (M = Yb3+ or Ga3+) [J].

Ahmed, Istaq ;

Rahman, Seikh M. H. ;

Steegstra, Patrick ;

Norberg, Stefan T. ;

Eriksson, Sten-G. ;

Ahlberg, Elisabet ;

Knee, Chris S. ;

Hull, Stephen .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (12) :6381-6391

[2] Enhanced low-temperature protonic conductivity in fully dense nanometric cubic zirconia [J].

Anselmi-Tamburini, Umberto ;

Maglia, Filippo ;

Chiodelli, Gaetano ;

Riello, Pietro ;

Bucella, Stefania ;

Munir, Zuhair A. .

APPLIED PHYSICS LETTERS, 2006, 89 (16)

[3] Enhanced sintering of yttrium-doped barium zirconate by addition of ZnO [J].

Babilo, P ;

Haile, SM .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (09) :2362-2368

[4]

Babilo P, 2007, J MATER RES, V22, P1322, DOI 10.1557/JMR.2007.0163

[5] CORRELATION BETWEEN IMPEDANCE, MICROSTRUCTURE AND COMPOSITION OF CALCIA-STABILIZED ZIRCONIA [J].

BEEKMANS, NM ;

HEYNE, L .

ELECTROCHIMICA ACTA, 1976, 21 (04) :303-310

[6] Defect thermodynamics and electrical properties of nanocrystalline oxides: Pure and doped CeO2 [J].

Chiang, YM ;

Lavik, EB ;

Blom, DA .

NANOSTRUCTURED MATERIALS, 1997, 9 (1-8) :633-642

[7] Defect and transport properties of nanocrystalline CeO2-x [J].

Chiang, YM ;

Lavik, EB ;

Kosacki, I ;

Tuller, HL ;

Ying, JY .

APPLIED PHYSICS LETTERS, 1996, 69 (02) :185-187

[8] Characterization of low temperature protonic conductivity in bulk nanocrystalline fully stabilized zirconia [J].

Chiodelli, Gaetano ;

Maglia, Filippo ;

Anselmi-Tamburini, Umberto ;

Munir, Zuhair A. .

SOLID STATE IONICS, 2009, 180 (4-5) :297-301

[9] Comprehensive Modeling of Ion Conduction of Nanosized CaF2/BaF2 Multilayer Heterostructures [J].

Guo, Xiangxin ;

Maier, Joachim .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (01) :96-101

[10] The role of microstructure and processing on the proton conducting properties of gadolinium-doped barium cerate [J].

Haile, SM ;

West, DL ;

Campbell, J .

JOURNAL OF MATERIALS RESEARCH, 1998, 13 (06) :1576-1595

← 1 2 3 4 →