Enhanced low-temperature protonic conductivity in fully dense nanometric cubic zirconia

被引:45
作者
Anselmi-Tamburini, Umberto [1 ]
Maglia, Filippo
Chiodelli, Gaetano
Riello, Pietro
Bucella, Stefania
Munir, Zuhair A.
机构
[1] Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA
[2] Univ Pavia, Dept Chem Phys, I-27100 Pavia, Italy
[3] CNR, IENI, Sez Pavia, I-27100 Pavia, Italy
[4] Univ Venice, Dept Chem Phys, I-30121 Venice, Italy
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2360934
中图分类号
O59 [应用物理学];
学科分类号
摘要
The authors report on the consolidation of nanostructured bulk cubic zirconia with a grain size of about 15 nm and a relative density greater than 98%. This material exhibits a change in the conduction mechanism with considerable protonic conductivity when exposed to moisture. The marked reduction of the resistivity of zirconia at low temperatures brings it to a level comparable to that typical of other protonic conductors, but with the advantage of superior mechanical and chemical stabilities.
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页数:3
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