Highly efficient, mild and chemo- and stereoselective synthesis of enaminones and enamino esters using silica supported perchloric acid under solvent-free conditions

被引：87

作者：

Das, B ^{[1
]}

Venkateswarlu, K ^{[1
]}

Majhi, A ^{[1
]}

Reddy, MR ^{[1
]}

Reddy, KN ^{[1
]}

Rao, YK ^{[1
]}

Ravikumar, K ^{[1
]}

Sridhar, B ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 246卷 / 1-2期

关键词：

beta-dicarbonyl compound; beta-enaminone; beta-enamino ester; HClO4 center dot SiO2; recyclable heterogeneous catalyst; solvent-free conditions;

D O I：

10.1016/j.molcata.2005.11.045

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Silica supported perchloric acid (HClO4 center dot SiO2) has been utilized as a heterogeneous recyclable catalyst for a highly efficient and chemo- and stereoselective conversion of beta-dicarbonyl compounds by treatment with amines at room temperature into beta-enaminones and beta-enamino esters under solvent-free conditions. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：276 / 281

页数：6

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