Controlled detitanation of ETS-10 materials through the post-synthetic treatment and their applications to the liquid-phase epoxidation of alkenes

被引：29

作者：

Goa, Y

Yoshitake, H

Wu, P

Tatsumi, T

机构：

[1] Yokohama Natl Univ, Grad Sch Engn, Div Mat Sci & Chem Engn, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan

[2] Univ Tokyo, Grad Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[3] Yokohama Natl Univ, Grad Sch Environm & Informat Sci, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2004年 / 70卷 / 1-3期

关键词：

ETS-10; titanosilicate; detitanation; epoxidation;

D O I：

10.1016/j.micromeso.2004.03.007

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Treatments of ETS-10 titanosilicates with HCl, NH4Cl or citric acid led to the change in the coordination environment of Ti. These treatments also led to the partial extraction of Ti from the framework of ETS-10. The local structural changes brought about the formation of the active sites for the epoxidation of cyclohexene with H2O2. The highest epoxidation activity and efficiency of H2O2 as an oxidant were achieved when the original [Na, K]-type ETS-10 was treated with 3.7 mol dm(-3) NH4Cl solution followed by the calcination at 723 K. (C) 2004 Elsevier Inc. All rights reserved.

引用

收藏

页码：93 / 101

页数：9

相关论文

共 32 条

[1] MICROPOROUS TITANOSILICATE ETS-10 - A STRUCTURAL SURVEY [J].

ANDERSON, MW ;

TERASAKI, O ;

OHSUNA, T ;

MALLEY, PJO ;

PHILIPPOU, A ;

MACKAY, SP ;

FERREIRA, A ;

ROCHA, J ;

LIDIN, S .

PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1995, 71 (05) :813-841

[2] STRUCTURE OF THE MICROPOROUS TITANOSILICATE ETS-10 [J].

ANDERSON, MW ;

TERASAKI, O ;

OHSUNA, T ;

PHILIPPOU, A ;

MACKAY, SP ;

FERREIRA, A ;

ROCHA, J ;

LIDIN, S .

NATURE, 1994, 367 (6461) :347-351

[3]

[Anonymous], 1989, US Patent, Patent No. [US4853202 A, 4853202]

[4]

Balkus KJ, 1995, STUD SURF SCI CATAL, V97, P519

[5] SYNTHESIS, CHARACTERIZATION, AND CATALYTIC ACTIVITY OF TI-MCM-41 STRUCTURES [J].

BLASCO, T ;

CORMA, A ;

NAVARRO, MT ;

PARIENTE, JP .

JOURNAL OF CATALYSIS, 1995, 156 (01) :65-74

[6] THE STATE OF TI IN TITANOALUMINOSILICATES ISOMORPHOUS WITH ZEOLITE-BETA [J].

BLASCO, T ;

CAMBLOR, MA ;

CORMA, A ;

PEREZPARIENTE, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) :11806-11813

[7] SYNTHESIS OF TITANOALUMINOSILICATES ISOMORPHOUS TO ZEOLITE BETA, ACTIVE AS OXIDATION CATALYSTS [J].

CAMBLOR, MA ;

CORMA, A ;

PEREZPARIENTE, J .

ZEOLITES, 1993, 13 (02) :82-87

[8] SYNTHESIS OF A TITANIUMSILICOALUMINATE ISOMORPHOUS TO ZEOLITE-BETA AND ITS APPLICATION AS A CATALYST FOR THE SELECTIVE OXIDATION OF LARGE ORGANIC-MOLECULES [J].

CAMBLOR, MA ;

CORMA, A ;

MARTINEZ, A ;

PEREZPARIENTE, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (08) :589-590

[9] EPOXIDATION OF LOWER OLEFINS WITH HYDROGEN-PEROXIDE AND TITANIUM SILICALITE [J].

CLERICI, MG ;

INGALLINA, P .

JOURNAL OF CATALYSIS, 1993, 140 (01) :71-83

[10] Synthesis and catalytic activity of Ti-ITQ-7:: a new oxidation catalyst with a three-dimensional system of large pore channels [J].

Díaz-Cabaña, MJ ;

Villaescusa, LA ;

Camblor, MA .

CHEMICAL COMMUNICATIONS, 2000, (09) :761-762

← 1 2 3 4 →