Effect of purification on pore structure of HiPco single-walled carbon nanotube aggregates

被引:94
作者
Yang, CM
Kaneko, K
Yudasaka, M
Iijima, S
机构
[1] NEC Corp Ltd, Japan Sci & Technol Corp, Tsukuba, Ibaraki 3058501, Japan
[2] Meijo Univ, Dept Phys, Tempa Ku, Nagoya, Aichi 4688502, Japan
[3] Chiba Univ, Fac Sci, Dept Chem, Inage Ku, Chiba 2638522, Japan
[4] Chiba Univ, Ctr Frontier Electron & Photon, Chiba 2638522, Japan
关键词
D O I
10.1021/nl015652f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
HiPco single-walled carbon nanotube (HPNT) containing Fe was purified by one-step purification with HCI-washing (D-method) and two-step purification with HCI-washing after air oxidation (GD-method). The N-2 adsorption isotherm of HPNT at 77 K is of type If and it changes to type IV after purification. Purification by the 0 and GD methods increases the total surface area and micropore volume, and it decreases the average pore width from 3.5 nm to 1.7 and 1.0 nm, respectively.
引用
收藏
页码:385 / 388
页数:4
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