Ligand effects in homogeneous Au catalysis

被引:1804
作者
Gorin, David J. [1 ]
Sherry, Benjamin D. [1 ]
Toste, F. Dean [1 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
D O I
10.1021/cr068430g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The solutions with the problems regarding the ligand effects in homogeneous catalysis through December 2007 has been given. Specifically, the problems with the obvious differences in reactivity and selectivity that comes from changing neutral or anionic ligands will be addressed with a focus on ligands and complexes that enables enantioselective catalysis. There are at times when catalyst choice gives off better improvement within the reaction yields or efficiencies. Meanwhile, an emphasis will be given on the privileged ligands and catalysts for a given class of reactions. Finally, the Hayashi/Ito asymmetric aldol reaction will be dealt with.
引用
收藏
页码:3351 / 3378
页数:28
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共 252 条
  • [1] Reversible C-F bond formation and the Au-catalyzed hydrofluorination of alkynes
    Akana, Jennifer A.
    Bhattacharyya, Koyel X.
    Mueller, Peter
    Sadighi, Joseph P.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (25) : 7736 - +
  • [2] ASYMMETRIC-SYNTHESIS OF ACIDS BY THE PALLADIUM-CATALYZED HYDROCARBOXYLATION OF OLEFINS IN THE PRESENCE OF (R)-(-)-1,1'-BINAPHTHYL-2,2'-DIYL OR (S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE
    ALPER, H
    HAMEL, N
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (07) : 2803 - 2804
  • [3] Gold-catalyzed addition of carbon nucleophiles to propargyl carboxylates
    Amijs, Catelijne H. M.
    Opez-Carrillo, Veronica
    Echavarren, Antonio M.
    [J]. ORGANIC LETTERS, 2007, 9 (20) : 4021 - 4024
  • [4] Gold(I)-catalysed arylation of 1,6-enynes: different site reactivity of cyclopropyl gold carbenes
    Amijs, Catelijne H. M.
    Ferrer, Catalina
    Echavarren, Antonio M.
    [J]. CHEMICAL COMMUNICATIONS, 2007, (07) : 698 - 700
  • [5] Lewis acid-catalyzed benzannulation via unprecedented [4+2] cycloaddition of o-alkynyl(oxo)benzenes and enynals with alkynes
    Asao, N
    Nogami, T
    Lee, S
    Yamamoto, Y
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (36) : 10921 - 10925
  • [6] AuCl3-catalyzed benzannulation:: Synthesis of naphthyl ketone derivatives from o-alkynylbenzaldehydes with alkynes
    Asao, N
    Takahashi, K
    Lee, S
    Kasahara, T
    Yamamoto, Y
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (43) : 12650 - 12651
  • [7] COINAGE METAL-CATALYZED HYDROBORATION OF IMINES
    BAKER, RT
    CALABRESE, JC
    WESTCOTT, SA
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 498 (02) : 109 - 117
  • [8] TRANSITION-METAL-CATALYZED DIBORATION OF VINYLARENES
    BAKER, RT
    NGUYEN, P
    MARDER, TB
    WESTCOTT, SA
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (12): : 1336 - 1338
  • [9] Room temperature hydroamination of N-alkenyl ureas catalyzed by a gold(I) N-heterocyclic carbene complex
    Bender, Christopher F.
    Widenhoefer, Ross A.
    [J]. ORGANIC LETTERS, 2006, 8 (23) : 5303 - 5305
  • [10] Gold(I)-catalyzed intramolecular hydroamination of unactivated alkenes with carboxamides
    Bender, Christopher F.
    Widenhoefer, Ross A.
    [J]. CHEMICAL COMMUNICATIONS, 2006, (39) : 4143 - 4144