Fluorination of "brick and mortar" soft-templated graphitic ordered mesoporous carbons for high power lithium-ion battery

被引:24
作者
Fulvio, Pasquale F. [1 ]
Veith, Gabriel M. [2 ]
Adcock, Jamie L. [3 ]
Brown, Suree S. [3 ]
Mayes, Richard T. [1 ]
Wang, Xiqing [1 ]
Mahurin, Shannon M. [1 ]
Guo, Bingkun [1 ]
Sun, Xiao-Guang [1 ]
Puretzky, Alex A. [4 ]
Rouleau, Christopher M. [4 ]
Geohegan, David B. [4 ]
Dai, Sheng [1 ,3 ]
机构
[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[2] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA
[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
[4] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA
关键词
PETROLEUM COKES; PERFORMANCE; FRAMEWORKS; POLYMERS;
D O I
10.1039/c3ta10710h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ordered mesoporous carbon-graphitic carbon composites prepared by the "brick and mortar" method were fluorinated using F-2 and investigated as cathodes for primary lithium batteries. The resulting materials have a rich array of C-F species, as measured by XPS, which influence conduction and voltage profiles.
引用
收藏
页码:9414 / 9417
页数:4
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